(+/-)-Hydroxymethyl-8-phenyl-1,6,8-triaza(2-13C)bicyclo[4.3.0]non-3-ene-7,9-dione

Base Information

Chemical Name:(+/-)-Hydroxymethyl-8-phenyl-1,6,8-triaza(2-13C)bicyclo[4.3.0]non-3-ene-7,9-dione
CAS No.:260261-48-1
Molecular Formula:C₁₃H₁₃N₃O₃
Molecular Weight:260.254
Hs Code.:

Synonyms:(+/-)-Hydroxymethyl-8-phenyl-1,6,8-triaza(2-13C)bicyclo[4.3.0]non-3-ene-7,9-dione

Suppliers and Price of (+/-)-Hydroxymethyl-8-phenyl-1,6,8-triaza(2-13C)bicyclo[4.3.0]non-3-ene-7,9-dione

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (+/-)-Hydroxymethyl-8-phenyl-1,6,8-triaza(2-13C)bicyclo[4.3.0]non-3-ene-7,9-dione

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Technology Process of (+/-)-Hydroxymethyl-8-phenyl-1,6,8-triaza(2-13C)bicyclo[4.3.0]non-3-ene-7,9-dione

There total 5 articles about (+/-)-Hydroxymethyl-8-phenyl-1,6,8-triaza(2-13C)bicyclo[4.3.0]non-3-ene-7,9-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₁₂⁽¹³⁾CH₁₀ClN₃O₃

: 260261-48-1
(+/-)-Hydroxymethyl-8-phenyl-1,6,8-triaza(2-13C)bicyclo[4.3.0]non-3-ene-7,9-dione

Guidance literature:: With sodium tetrahydroborate; In 1,4-dioxane; water; at 10 ℃; for 2h;
DOI:10.1039/a907365e

Reference yield:

: 4233-33-4
4-Phenyl-1,2,4-triazolidine-3,5-dione

: 260261-48-1
(+/-)-Hydroxymethyl-8-phenyl-1,6,8-triaza(2-13C)bicyclo[4.3.0]non-3-ene-7,9-dione

Guidance literature:: Multi-step reaction with 3 steps

1: ethyl acetate / 18 h / 20 °C

2: SOCl₂ / 1.5 h / Heating

3: NaBH₄ / dioxane; H₂O / 2 h / 10 °C

With sodium tetrahydroborate; thionyl chloride; In 1,4-dioxane; water; ethyl acetate; 1: Cyclization / 2: Substitution / 3: Reduction;
DOI:10.1039/a907365e

Reference yield:

: 15988-11-1
4-Phenylurazole

: 260261-48-1
(+/-)-Hydroxymethyl-8-phenyl-1,6,8-triaza(2-13C)bicyclo[4.3.0]non-3-ene-7,9-dione

Guidance literature:: Multi-step reaction with 4 steps

1: tert-butyl hypochlorite / ethyl acetate / 0.17 h / 0 °C

2: ethyl acetate / 18 h / 20 °C

3: SOCl₂ / 1.5 h / Heating

4: NaBH₄ / dioxane; H₂O / 2 h / 10 °C

With sodium tetrahydroborate; thionyl chloride; tert-butylhypochlorite; In 1,4-dioxane; water; ethyl acetate; 1: Oxidation / 2: Cyclization / 3: Substitution / 4: Reduction;
DOI:10.1039/a907365e