6-aminohexyl 3,4,6-tri-O-acetyl-2-O-benzoyl-β-D-mannopyranosyl-(1->4)-[2,3,4-tri-O-acetyl-α-L-fucopyanosyl-(1->3)]-2-O-benzoyl-6-O-acetyl-β-D-glucopyranoside

Base Information

• Chemical Name: 6-aminohexyl 3,4,6-tri-O-acetyl-2-O-benzoyl-β-D-mannopyranosyl-(1->4)-[2,3,4-tri-O-acetyl-α-L-fucopyanosyl-(1->3)]-2-O-benzoyl-6-O-acetyl-β-D-glucopyranoside
• CAS No.: 904319-38-6
• Molecular Formula: C₅₂H₆₇NO₂₄
• Molecular Weight: 1090.1
• Mol file: 904319-38-6.mol

Synonyms:6-aminohexyl 3,4,6-tri-O-acetyl-2-O-benzoyl-β-D-mannopyranosyl-(1->4)-[2,3,4-tri-O-acetyl-α-L-fucopyanosyl-(1->3)]-2-O-benzoyl-6-O-acetyl-β-D-glucopyranoside

Chemical Property of 6-aminohexyl 3,4,6-tri-O-acetyl-2-O-benzoyl-β-D-mannopyranosyl-(1->4)-[2,3,4-tri-O-acetyl-α-L-fucopyanosyl-(1->3)]-2-O-benzoyl-6-O-acetyl-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 6-aminohexyl 3,4,6-tri-O-acetyl-2-O-benzoyl-β-D-mannopyranosyl-(1->4)-[2,3,4-tri-O-acetyl-α-L-fucopyanosyl-(1->3)]-2-O-benzoyl-6-O-acetyl-β-D-glucopyranoside

There total 5 articles about 6-aminohexyl 3,4,6-tri-O-acetyl-2-O-benzoyl-β-D-mannopyranosyl-(1->4)-[2,3,4-tri-O-acetyl-α-L-fucopyanosyl-(1->3)]-2-O-benzoyl-6-O-acetyl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

6-N-(2,2,2-trichloroethoxycarbonyl)aminohexyl 3,4,6-tri-O-acetyl-2-O-benzoyl-β-D-mannopyranosyl-(1->4)-[2,3,4-tri-O-acetyl-α-L-fucopyranosyl-(1->3)]-2-O-benzoyl-6-O-acetyl-β-D-glucopyranoside (904319-37-5) → 6-aminohexyl 3,4,6-tri-O-acetyl-2-O-benzoyl-β-D-mannopyranosyl-(1->4)-[2,3,4-tri-O-acetyl-α-L-fucopyanosyl-(1->3)]-2-O-benzoyl-6-O-acetyl-β-D-glucopyranoside (904319-38-6)

Guidance literature:

With acetic acid; zinc; at 20 ℃; for 16h;

DOI:10.1016/j.carres.2006.04.019

Reference yield:

N-(2,2,2-trichloroethoxycarbonyl)hexanolamine (146292-94-6) → 6-aminohexyl 3,4,6-tri-O-acetyl-2-O-benzoyl-β-D-mannopyranosyl-(1->4)-[2,3,4-tri-O-acetyl-α-L-fucopyanosyl-(1->3)]-2-O-benzoyl-6-O-acetyl-β-D-glucopyranoside (904319-38-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 100 percent / AW₃₀₀ molecular sieves; TMSOTf / CH₂Cl₂ / 4 h / 0 °C

2: 100 percent / HOAc; zinc powder / 16 h / 20 °C

With molecular sieve; trimethylsilyl trifluoromethanesulfonate; acetic acid; zinc; In dichloromethane;

DOI:10.1016/j.carres.2006.04.019

Reference yield:

2-(trimethylsilyl)ethyl 3,4,6-tri-O-acetyl-2-O-benzoyl-β-D-mannopyranosyl-(1->4)-[2,3,4-tri-O-acetyl-α-L-fucopyranosyl-(1->3)]-2-O-benzoyl-6-O-acetyl-β-D-glucopyranoside (904319-34-2) → 6-aminohexyl 3,4,6-tri-O-acetyl-2-O-benzoyl-β-D-mannopyranosyl-(1->4)-[2,3,4-tri-O-acetyl-α-L-fucopyanosyl-(1->3)]-2-O-benzoyl-6-O-acetyl-β-D-glucopyranoside (904319-38-6)

Guidance literature:

Multi-step reaction with 3 steps

1.1: CF₃CO₂H / CH₂Cl₂ / 2.5 h / 0 - 20 °C

1.2: 86 percent / DBU / CH₂Cl₂ / 2 h / 0 °C

2.1: 100 percent / AW₃₀₀ molecular sieves; TMSOTf / CH₂Cl₂ / 4 h / 0 °C

3.1: 100 percent / HOAc; zinc powder / 16 h / 20 °C

With molecular sieve; trimethylsilyl trifluoromethanesulfonate; acetic acid; trifluoroacetic acid; zinc; In dichloromethane;

DOI:10.1016/j.carres.2006.04.019

upstream raw materials:

6-N-(2,2,2-trichloroethoxycarbonyl)aminohexyl 3,4,6-tri-O-acetyl-2-O-benzoyl-β-D-mannopyranosyl-(1->4)-[2,3,4-tri-O-acetyl-α-L-fucopyranosyl-(1->3)]-2-O-benzoyl-6-O-acetyl-β-D-glucopyranoside

N-(2,2,2-trichloroethoxycarbonyl)hexanolamine

2-(trimethylsilyl)ethyl 3,4,6-tri-O-acetyl-2-O-benzoyl-β-D-mannopyranosyl-(1->4)-[2,3,4-tri-O-acetyl-α-L-fucopyranosyl-(1->3)]-2-O-benzoyl-6-O-acetyl-β-D-glucopyranoside

3,4,6-tri-O-acetyl-2-O-benzoyl-β-D-mannopyranosyl-(1->4)-[2,3,4-tri-O-acetyl-α-L-fucopyranosyl-(1->3)]-2-O-benzoyl-6-O-acetyl-α-D-glucopyranosyl trichloroacetimidate

Downstream raw materials:

C₆₄H₈₃Cl₃N₂O₂₉

C₆₂H₈₂N₂O₂₉