6-dodecyl-6-(2-methoxybenzyl)-1,4,8,11-tetraoxacyclotetradecane

Base Information

• Chemical Name: 6-dodecyl-6-(2-methoxybenzyl)-1,4,8,11-tetraoxacyclotetradecane
• CAS No.: 98514-81-9
• Molecular Formula: C₃₀H₅₂O₅
• Molecular Weight: 492.74
• Mol file: 98514-81-9.mol

Synonyms:6-dodecyl-6-(2-methoxybenzyl)-1,4,8,11-tetraoxacyclotetradecane

Chemical Property of 6-dodecyl-6-(2-methoxybenzyl)-1,4,8,11-tetraoxacyclotetradecane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 6-dodecyl-6-(2-methoxybenzyl)-1,4,8,11-tetraoxacyclotetradecane

There total 1 articles about 6-dodecyl-6-(2-methoxybenzyl)-1,4,8,11-tetraoxacyclotetradecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3,7-dioxanonane-1,9-diylbis(toluene-p-sulphonate) (92144-75-7) + 2-dodecyl-2-(2'-methoxybenzyl)propane-1,3-diol (98506-66-2) → 6-dodecyl-6-(2-methoxybenzyl)-1,4,8,11-tetraoxacyclotetradecane (98514-81-9)

Guidance literature:

With lithium perchlorate; sodium hydride; In 1,4-dioxane; Heating;

DOI:10.1039/c39850000669

Reference yield: 60.0%

6-dodecyl-6-(2-methoxybenzyl)-1,4,8,11-tetraoxacyclotetradecane (98514-81-9) → 2-(dodecyl-14-crown-4)phenol (98506-67-3)

Guidance literature:

With lithium aluminium tetrahydride; In octane; for 8h; Heating;

DOI:10.1021/jo00381a023

Reference yield:

6-dodecyl-6-(2-methoxybenzyl)-1,4,8,11-tetraoxacyclotetradecane (98514-81-9) → 6-dodecyl-6-(2-hydroxy-3,5-dinitrobenzyl)-1,4,8,11-tetraoxacyclotetradecane (98506-70-8)

Guidance literature:

Multi-step reaction with 2 steps

1: LiAlH₄ / heptane / Heating

2: HNO₃ / CHCl₃ / Ambient temperature

With lithium aluminium tetrahydride; nitric acid; In n-heptane; chloroform;

DOI:10.1039/c39850000669

upstream raw materials:

3,7-dioxanonane-1,9-diylbis(toluene-p-sulphonate)

2-dodecyl-2-(2'-methoxybenzyl)propane-1,3-diol

Downstream raw materials:

2-(dodecyl-14-crown-4)phenol

6-dodecyl-6-(2-hydroxy-3-nitrobenzyl)-1,4,8,11-tetraoxacyclotetradecane

6-dodecyl-6-(2-hydroxy-5-nitrobenzyl)-1,4,8,11-tetraoxacyclotetradecane

6-dodecyl-6-(2-hydroxy-3,5-dinitrobenzyl)-1,4,8,11-tetraoxacyclotetradecane