C₂₃H₃₄O₂Si

Base Information

• Chemical Name: C₂₃H₃₄O₂Si
• CAS No.: 1310330-11-0
• Molecular Formula: C₂₃H₃₄O₂Si
• Molecular Weight: 370.607
• Mol file: 1310330-11-0.mol

Synonyms:C₂₃H₃₄O₂Si

Chemical Property of C₂₃H₃₄O₂Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₃H₃₄O₂Si

There total 7 articles about C₂₃H₃₄O₂Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

C25H38O2Si (1310330-45-0) → C23H34O2Si (1310330-11-0)

Guidance literature:

With 1,3-bis-(2,4,6-trimethylphenyl)-2-(imidazolidinylidene)dichloro(5-nitro-2-isopropoxyphenylmethylene)ruthenium; tricyclohexylphosphine oxide; In toluene; at 60 ℃; for 24h; stereoselective reaction; Inert atmosphere;

DOI:10.1021/ja2031085

Reference yield:

5-(benzyldimethylsilyl)pent-4-yn-1-ol (460752-64-1) → C23H34O2Si (1310330-11-0)

Guidance literature:

Multi-step reaction with 4 steps

1.1: triethylaluminum / dichloromethane; toluene / 0 - 20 °C / Inert atmosphere

1.2: 58 h / 20 °C / Inert atmosphere

1.3: 1 h / -78 - 0 °C / Inert atmosphere

2.1: dichloro bis(acetonitrile) palladium(II); Tetrabutylammoniumsalz der Diphenylphosphinsaeure / N,N-dimethyl-formamide / 1 h / Inert atmosphere

3.1: 4-pyrrolidin-1-ylpyridine; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride / dichloromethane / 1 h / Inert atmosphere

4.1: 1,3-bis-(2,4,6-trimethylphenyl)-2-(imidazolidinylidene)dichloro(5-nitro-2-isopropoxyphenylmethylene)ruthenium; tricyclohexylphosphine oxide / toluene / 24 h / 60 °C / Inert atmosphere

With dichloro bis(acetonitrile) palladium(II); 1,3-bis-(2,4,6-trimethylphenyl)-2-(imidazolidinylidene)dichloro(5-nitro-2-isopropoxyphenylmethylene)ruthenium; tricyclohexylphosphine oxide; triethylaluminum; 4-pyrrolidin-1-ylpyridine; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; Tetrabutylammoniumsalz der Diphenylphosphinsaeure; In dichloromethane; N,N-dimethyl-formamide; toluene;

DOI:10.1021/ja2031085

Reference yield:

(Z)-5-(Benzyl-dimethyl-silanyl)-5-iodo-pent-4-en-1-ol → C23H34O2Si (1310330-11-0)

Guidance literature:

Multi-step reaction with 3 steps

1: dichloro bis(acetonitrile) palladium(II); Tetrabutylammoniumsalz der Diphenylphosphinsaeure / N,N-dimethyl-formamide / 1 h / Inert atmosphere

2: 4-pyrrolidin-1-ylpyridine; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride / dichloromethane / 1 h / Inert atmosphere

3: 1,3-bis-(2,4,6-trimethylphenyl)-2-(imidazolidinylidene)dichloro(5-nitro-2-isopropoxyphenylmethylene)ruthenium; tricyclohexylphosphine oxide / toluene / 24 h / 60 °C / Inert atmosphere

With dichloro bis(acetonitrile) palladium(II); 1,3-bis-(2,4,6-trimethylphenyl)-2-(imidazolidinylidene)dichloro(5-nitro-2-isopropoxyphenylmethylene)ruthenium; tricyclohexylphosphine oxide; 4-pyrrolidin-1-ylpyridine; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; Tetrabutylammoniumsalz der Diphenylphosphinsaeure; In dichloromethane; N,N-dimethyl-formamide; toluene;

DOI:10.1021/ja2031085

upstream raw materials:

5-(benzyldimethylsilyl)pent-4-yn-1-ol

5-(benzyldimethylsilyl)-1-(tetrahydropyran-2′-yloxy)pent-4-yne

1-(tetrahydropyranyloxy)-4-pentyn

C₁₆H₂₄OSi