(E)-3-(3-(benzyloxy)-4-methoxyphenyl)allyl 3-(benzo[d][1,3]dioxol-5-yl)propiolate

Base Information

Chemical Name:(E)-3-(3-(benzyloxy)-4-methoxyphenyl)allyl 3-(benzo[d][1,3]dioxol-5-yl)propiolate
CAS No.:1544344-02-6
Molecular Formula:C₂₇H₂₂O₆
Molecular Weight:442.468
Hs Code.:

Synonyms:(E)-3-(3-(benzyloxy)-4-methoxyphenyl)allyl 3-(benzo[d][1,3]dioxol-5-yl)propiolate

Suppliers and Price of (E)-3-(3-(benzyloxy)-4-methoxyphenyl)allyl 3-(benzo[d][1,3]dioxol-5-yl)propiolate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (E)-3-(3-(benzyloxy)-4-methoxyphenyl)allyl 3-(benzo[d][1,3]dioxol-5-yl)propiolate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (E)-3-(3-(benzyloxy)-4-methoxyphenyl)allyl 3-(benzo[d][1,3]dioxol-5-yl)propiolate

There total 8 articles about (E)-3-(3-(benzyloxy)-4-methoxyphenyl)allyl 3-(benzo[d][1,3]dioxol-5-yl)propiolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 3-(3-benzyloxy-4-methoxy-phenyl)prop-2-en-1-ol

: 10231-46-6
3-(benzo[d][1,3]dioxol-5-yl)propiolic acid

: 1544344-02-6
(E)-3-(3-(benzyloxy)-4-methoxyphenyl)allyl 3-(benzo[d][1,3]dioxol-5-yl)propiolate

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 0 - 20 ℃;
DOI:10.1016/j.tetlet.2013.12.014

Reference yield:

: 31893-02-4
3-(benzo[d][1,3]dioxol-5-yl)propionic acid methyl ester

: 1544344-02-6
(E)-3-(3-(benzyloxy)-4-methoxyphenyl)allyl 3-(benzo[d][1,3]dioxol-5-yl)propiolate

Guidance literature:: Multi-step reaction with 2 steps

1: potassium carbonate / ethanol / 20 °C

2: dicyclohexyl-carbodiimide; dmap / dichloromethane / 0 - 20 °C

With dmap; potassium carbonate; dicyclohexyl-carbodiimide; In ethanol; dichloromethane;
DOI:10.1016/j.tetlet.2013.12.014

Reference yield:

: 120-57-0,30024-74-9
piperonal

: 1544344-02-6
(E)-3-(3-(benzyloxy)-4-methoxyphenyl)allyl 3-(benzo[d][1,3]dioxol-5-yl)propiolate

Guidance literature:: Multi-step reaction with 4 steps

1.1: triphenylphosphine / dichloromethane / 20 °C

2.1: n-butyllithium / tetrahydrofuran / -78 °C

2.2: -78 - 20 °C

3.1: potassium carbonate / ethanol / 20 °C

4.1: dicyclohexyl-carbodiimide; dmap / dichloromethane / 0 - 20 °C

With dmap; n-butyllithium; potassium carbonate; dicyclohexyl-carbodiimide; triphenylphosphine; In tetrahydrofuran; ethanol; dichloromethane; 2.1: |Corey-Fuchs Alkyne Synthesis / 2.2: |Corey-Fuchs Alkyne Synthesis;
DOI:10.1016/j.tetlet.2013.12.014