methyl 4-(3-bromophenoxy)butanoate

Base Information

Chemical Name:methyl 4-(3-bromophenoxy)butanoate
CAS No.:1096893-57-0
Molecular Formula:C₁₁H₁₃BrO₃
Molecular Weight:273.126
Hs Code.:

Synonyms:methyl 4-(3-bromophenoxy)butanoate

Suppliers and Price of methyl 4-(3-bromophenoxy)butanoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of methyl 4-(3-bromophenoxy)butanoate

Chemical Property:

Purity/Quality:: 99%, ^*data from raw suppliers

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Technology Process of methyl 4-(3-bromophenoxy)butanoate

There total 1 articles about methyl 4-(3-bromophenoxy)butanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 4897-84-1
Methyl 4-bromobutyrate

: 591-20-8
3-Bromophenol

: 1096893-57-0
methyl 4-(3-bromophenoxy)butanoate

Guidance literature:: With potassium carbonate; In N,N-dimethyl-formamide; at 20 - 90 ℃; for 1.5h;

Reference yield: 99.0%

: 1096893-57-0
methyl 4-(3-bromophenoxy)butanoate

: 170638-88-7
4-(3-bromophenoxy)butanoic acid

Guidance literature:: methyl 4-(3-bromophenoxy)butanoate; With water; sodium hydroxide; In methanol; at 65 ℃; for 0.5h;

With hydrogenchloride; In water; pH=~ 2;

Reference yield:

: 1096893-57-0
methyl 4-(3-bromophenoxy)butanoate

: (7aRS,11aRS)-11a-ethyl-N-(2-methylpyridin-3-yl)-9-phenyl-6,7,7a,8,11,11a-hexahydrodibenzo[b,d]oxepine-3-carboxamide

Guidance literature:: Multi-step reaction with 16 steps

1.1: sodium hydroxide; water / methanol / 0.5 h / 65 °C

1.2: pH ~ 2

2.1: polyphosphoric acid / 0.5 h / 75 - 100 °C

3.1: sodium carbonate / dichloromethane / 16 h / 0 - 20 °C

4.1: triethylamine / 1,3-bis-(diphenylphosphino)propane; palladium diacetate / N,N-dimethyl-formamide / 2 h / 80 °C

5.1: toluene / 72 h / 125 °C / Sealed vessel

5.2: 6 h / 20 °C

6.1: sodium hydrogencarbonate; sodium dithionite / Aliquot_.(TM). 336 / water / 0.58 h / 100 °C

7.1: toluene-4-sulfonic acid / toluene / 1 h / Reflux

8.1: lithium aluminium tetrahydride / tetrahydrofuran / 0.92 h / -65 - 0 °C

8.2: -60 °C

9.1: Dess-Martin periodane / dichloromethane / 1.5 h / 20 °C

10.1: sodium hydride / dimethyl sulfoxide; tetrahydrofuran; mineral oil / 0.5 h / 20 °C

10.2: 18.17 h / 20 °C

11.1: triethylamine / 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾ / N,N-dimethyl-formamide / 14 h / 90 °C

12.1: hydrogen / platinum(IV) oxide / ethyl acetate / 2 h

13.1: lithium hexamethyldisilazane / toluene; tetrahydrofuran / 0.25 h / 0 °C

14.1: hydrogenchloride; water / tetrahydrofuran / 16 h / 20 °C

15.1: tetrahydrofuran / 1 h / 5 - 10 °C

16.1: toluene-4-sulfonic acid; potassium hydrogensulfate / toluene / 4.5 h / 110 °C

With hydrogenchloride; potassium hydrogensulfate; lithium aluminium tetrahydride; sodium dithionite; water; hydrogen; sodium hydride; sodium hydrogencarbonate; sodium carbonate; Dess-Martin periodane; toluene-4-sulfonic acid; triethylamine; sodium hydroxide; lithium hexamethyldisilazane; platinum(IV) oxide; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; 1,3-bis-(diphenylphosphino)propane; palladium diacetate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; In tetrahydrofuran; methanol; dichloromethane; water; dimethyl sulfoxide; ethyl acetate; N,N-dimethyl-formamide; toluene; mineral oil;