1-O-benzoyl 2,3-O-isopropylidene-α-D-lyxopentodialdehydo-1,4-furanoside

Base Information

• Chemical Name: 1-O-benzoyl 2,3-O-isopropylidene-α-D-lyxopentodialdehydo-1,4-furanoside
• CAS No.: 57492-91-8
• Molecular Formula: C₁₅H₁₆O₆
• Molecular Weight: 292.288
• Mol file: 57492-91-8.mol

Synonyms:1-O-benzoyl 2,3-O-isopropylidene-α-D-lyxopentodialdehydo-1,4-furanoside

Chemical Property of 1-O-benzoyl 2,3-O-isopropylidene-α-D-lyxopentodialdehydo-1,4-furanoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-O-benzoyl 2,3-O-isopropylidene-α-D-lyxopentodialdehydo-1,4-furanoside

There total 9 articles about 1-O-benzoyl 2,3-O-isopropylidene-α-D-lyxopentodialdehydo-1,4-furanoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

Benzoic acid (3aS,4R,6R,6aS)-6-(2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl ester → 1-O-benzoyl 2,3-O-isopropylidene-α-D-lyxopentodialdehydo-1,4-furanoside (57492-91-8)

Guidance literature:

With periodic acid; In diethyl ether; Ambient temperature;

DOI:10.1021/jo00065a025

Reference yield: 90.0%

1-O-benzoyl-2,3-O-isopropylidene-α-D-mannofuranose → 1-O-benzoyl 2,3-O-isopropylidene-α-D-lyxopentodialdehydo-1,4-furanoside (57492-91-8)

Guidance literature:

With polymer-supported phenyliodine(III) diacetate; In dichloromethane; at 20 ℃; for 6.5h;

DOI:10.1055/s-2007-970745

Reference yield:

1-O-benzoyl-2,3-O-isopropylidene-α-D-mannofuranoside (57492-90-7) → 1-O-benzoyl 2,3-O-isopropylidene-α-D-lyxopentodialdehydo-1,4-furanoside (57492-91-8)

Guidance literature:

With sodium periodate; In water; acetone; at 0 ℃; for 0.5h;

DOI:10.1016/0008-6215(84)85050-8

upstream raw materials:

1-O-benzoyl-2,3-O-isopropylidene-α-D-mannofuranoside

(+)-2,3:5,6-di-O-isopropylidene-α-D-mannofuranos-3-yl benzoate

benzoyl chloride

α-D-mannose

Downstream raw materials:

methyl 1-O-benzoyl-5,6,7,8-tetradeoxy-2,3-O-isopropylidene-D-lyxo-non-5,7-dienofuranuronate

(5Z)-1-O-benzoyl-5,6,7-trideoxy-2,3:8,9-di-O-isopropylidene-α-D-manno-non-5-enofuranoside

Benzoic acid (3aS,4R,6R,6aS)-6-[(E)-2-(diethoxy-phosphoryl)-vinyl]-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl ester

Benzoic acid (3aS,4R,6R,6aS)-6-[(E)-2-(diethoxy-phosphoryl)-2-fluoro-vinyl]-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl ester