RuCl2[(R)-xylbinap][(R)-daipen]

Base Information Edit

Chemical Name:RuCl2[(R)-xylbinap][(R)-daipen]
CAS No.:220114-32-9
Molecular Formula:C₇₁H₇₄Cl₂N₂O₂P₂Ru
Molecular Weight:1221.3
Hs Code.:
European Community (EC) Number:806-965-1
Mol file:220114-32-9.mol

Synonyms:RuCl2[(R)-xylbinap][(R)-daipen];220114-32-9;MFCD09753026;T72097;[1-[2-bis(3,5-dimethylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(3,5-dimethylphenyl)phosphane;(2R)-1,1-bis(4-methoxyphenyl)-3-methylbutane-1,2-diamine;dichlororuthenium

Suppliers and Price of RuCl2[(R)-xylbinap][(R)-daipen]

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
RuCl2[(R)?DM?binap][(R)?daipen]
50mg
$ 70.00

TCI Chemical
RuCl2[(R)-xylbinap][(R)-daipen]
200mg
$ 69.00

TCI Chemical
RuCl2[(R)-xylbinap][(R)-daipen]
1g
$ 234.00

Strem Chemicals
Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R)-daipen]
5g
$ 474.00

Strem Chemicals
Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R)-daipen]
1g
$ 190.00

Strem Chemicals
Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R)-daipen]
250mg
$ 64.00

Sigma-Aldrich
RuCl2[(R)?DM?BINAP][(R)?DAIPEN]
100mg
$ 51.00

Sigma-Aldrich
RuCl2[(R)?DM?BINAP][(R)?DAIPEN]
50mg
$ 24.50

Labseeker
RuCl2[(R)-xylbinap][(R)-daipen] 95
5g
$ 1685.00

Labseeker
RuCl2[(R)-xylbinap][(R)-daipen] 95
1g
$ 975.00

Total 9 raw suppliers

Chemical Property of RuCl2[(R)-xylbinap][(R)-daipen] Edit

Chemical Property:

Melting Point:197-211 °C
PSA：69.70000
LogP:18.32400
Storage Temp.:2-8°C
Sensitive.:air sensitive
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:13
Exact Mass:1220.364599
Heavy Atom Count:80
Complexity:1320

Purity/Quality:

98%,99%, ^*data from raw suppliers

RuCl2[(R)?DM?binap][(R)?daipen] ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:CC1=CC(=CC(=C1)P(C2=C(C3=CC=CC=C3C=C2)C4=C(C=CC5=CC=CC=C54)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C8=CC(=CC(=C8)C)C)C.CC(C)C(C(C1=CC=C(C=C1)OC)(C2=CC=C(C=C2)OC)N)N.Cl[Ru]Cl
Isomeric SMILES:CC1=CC(=CC(=C1)P(C2=C(C3=CC=CC=C3C=C2)C4=C(C=CC5=CC=CC=C54)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C8=CC(=CC(=C8)C)C)C.CC(C)[C@H](C(C1=CC=C(C=C1)OC)(C2=CC=C(C=C2)OC)N)N.Cl[Ru]Cl
Uses Chiral RuCl2(diphosphine)?(1,?2-?diamine) complexes catalyzes the asymetrical hydrogenation of amino ketones. E.g., hydrogenation of MeCOCH2NMe2 in presence of trans-?RuCl2[(R)?-?xylbinap]?[(R)?-?daipen] gave 79?% (S)?-?MeCH(OH)?CH2NMe2. This compound was used as a catalyst.

Technology Process of RuCl2[(R)-xylbinap][(R)-daipen]

There total 1 articles about RuCl2[(R)-xylbinap][(R)-daipen] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: