(2E,6E)-10-(tert-butyldiphenylsilyloxy)-3,7-dimethyldeca-2,6-dienyl diethyl phosphate

Base Information

Chemical Name:(2E,6E)-10-(tert-butyldiphenylsilyloxy)-3,7-dimethyldeca-2,6-dienyl diethyl phosphate
CAS No.:917611-93-9
Molecular Formula:C₃₂H₄₉O₅PSi
Molecular Weight:572.797
Hs Code.:

Synonyms:(2E,6E)-10-(tert-butyldiphenylsilyloxy)-3,7-dimethyldeca-2,6-dienyl diethyl phosphate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2E,6E)-10-(tert-butyldiphenylsilyloxy)-3,7-dimethyldeca-2,6-dienyl diethyl phosphate

Chemical Property:

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Technology Process of (2E,6E)-10-(tert-butyldiphenylsilyloxy)-3,7-dimethyldeca-2,6-dienyl diethyl phosphate

There total 7 articles about (2E,6E)-10-(tert-butyldiphenylsilyloxy)-3,7-dimethyldeca-2,6-dienyl diethyl phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 917611-87-1
(2E,6E)-10-(tert-butyldiphenylsilyloxy)-3,7-dimethyldeca-2,6-dien-1-ol

: 814-49-3
diethyl chlorophosphate

: 917611-93-9
(2E,6E)-10-(tert-butyldiphenylsilyloxy)-3,7-dimethyldeca-2,6-dienyl diethyl phosphate

Guidance literature:: With triethylamine; In hexane; at 0 - 20 ℃; for 24h;
DOI:10.1021/ol062378t

Reference yield:

: acetic acid 10-(tert-butyl-diphenyl-silanyloxy)-3,7-dimethyl-deca-2,6-dienyl ester

: 917611-93-9
(2E,6E)-10-(tert-butyldiphenylsilyloxy)-3,7-dimethyldeca-2,6-dienyl diethyl phosphate

Guidance literature:: Multi-step reaction with 2 steps

1: K₂CO₃ / methanol / 1 h / 20 °C

2: 91 percent / Et₃N / hexane / 24 h / 0 - 20 °C

With potassium carbonate; triethylamine; In methanol; hexane;
DOI:10.1021/ol062378t

Reference yield:

: 50502-44-8
10,11-epoxyfarnesyl acetate

: 917611-93-9
(2E,6E)-10-(tert-butyldiphenylsilyloxy)-3,7-dimethyldeca-2,6-dienyl diethyl phosphate

Guidance literature:: Multi-step reaction with 5 steps

1: HIO₄*2H₂O / diethyl ether; tetrahydrofuran / 0.5 h / 0 °C

2: NaBH₄ / ethanol / 1 h / 0 °C

3: imidazole / dimethylformamide / 0 °C

4: K₂CO₃ / methanol / 1 h / 20 °C

5: 91 percent / Et₃N / hexane / 24 h / 0 - 20 °C

With 1H-imidazole; sodium tetrahydroborate; potassium carbonate; periodic acid; triethylamine; In tetrahydrofuran; methanol; diethyl ether; ethanol; hexane; N,N-dimethyl-formamide;
DOI:10.1021/ol062378t