{(η5-C5H5)Re(NO)(PPh3)(η2-H2C=S)}(+)PF6(-)

Base Information

Chemical Name:{(η5-C5H5)Re(NO)(PPh3)(η2-H2C=S)}(+)PF6(-)
CAS No.:84369-18-6
Molecular Formula:C₂₄H₂₂NOPReS*F₆P
Molecular Weight:734.656
Hs Code.:

Synonyms:{(η5-C5H5)Re(NO)(PPh3)(η2-H2C=S)}(+)PF6(-)

Suppliers and Price of {(η5-C5H5)Re(NO)(PPh3)(η2-H2C=S)}(+)PF6(-)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of {(η5-C5H5)Re(NO)(PPh3)(η2-H2C=S)}(+)PF6(-)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of {(η5-C5H5)Re(NO)(PPh3)(η2-H2C=S)}(+)PF6(-)

There total 3 articles about {(η5-C5H5)Re(NO)(PPh3)(η2-H2C=S)}(+)PF6(-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 286-28-2
cyclohexene sulfide

: (η5-C5H5)(Me)(NO)(PPh3)rhenium(II)

: 437-17-2
tritylium hexafluorophosphate

: 84369-18-6
{(η5-C5H5)Re(NO)(PPh3)(η2-H2C=S)}(+)PF6(-)

Guidance literature:: In dichloromethane; Ph3CPF6 was added to a CH2Cl2 soln. of the Re-complex at -78°C with stirring under N2 atmosphere, after 1 h cyclohexene sulfide was added, mixt. was stirred for 1 h without cooling; evapd., residue was washed with hexane and ether, dissolved in CHCl3, pptd. crystals were collected by filtration and recrystd. by vapor diffusion using acetone-hexane; elem. anal.;

Reference yield: 64.0%

: (η5-C5H5)(Me)(NO)(PPh3)rhenium(II)

: 437-17-2
tritylium hexafluorophosphate

: 3878-45-3
triphenylphosphine sulfide

: 71763-25-2
{(η5-C5H5)Re(NO)(PPh3)(CH2PPh3)}(+)PF6(-)

: 84369-18-6
{(η5-C5H5)Re(NO)(PPh3)(η2-H2C=S)}(+)PF6(-)

Guidance literature:: In dichloromethane; Ph3CPF6 was added to a CH2Cl2 soln. of the Re-complex at -78°C with stirring under N2 atmosphere, after 15 min Ph3PS was added, and the flask was placed in a -23°C bath for 1 h; evapd. at room temp., residue (1:1 mixt. of Re-complexes - (1)H NMR data) was repptd. with Et2O from Me2CO, extd. with Me2CO (solid - mainly PPh3(+) complex - IR data), Et2O was added to exts., ppt. was washed with CH2Cl2, recrystd. from CH2Cl2-Et2O;