phenyl 3-phenyl-1-propenyl sulfone

Base Information

• Chemical Name: phenyl 3-phenyl-1-propenyl sulfone
• CAS No.: 133616-31-6
• Molecular Formula: C₁₅H₁₄O₂S
• Molecular Weight: 258.341
• Mol file: 133616-31-6.mol

Synonyms:(E)-((3-phenylprop-1-en-1-yl)sulfonyl)benzene

Chemical Property of phenyl 3-phenyl-1-propenyl sulfone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phenyl 3-phenyl-1-propenyl sulfone

There total 6 articles about phenyl 3-phenyl-1-propenyl sulfone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

allylbenzene (300-57-2,57807-91-7) + PVS (5535-48-8) → (E)-((3-phenylprop-1-en-1-yl)sulfonyl)benzene (133616-31-6)

Guidance literature:

Cl₂(=CH-C₆H₃-2-OiPr-5-NO₂)(1,3-dimesitylimidazolidin-2-yl)Ru; In dichloromethane; at 25 ℃;

DOI:10.1016/S0040-4020(03)00682-3

Reference yield: 81.0%

diethyl phenylsulfonylmethylphosphonate (56069-39-7) + phenylacetaldehyde (122-78-1) → (E)-((3-phenylprop-1-en-1-yl)sulfonyl)benzene (133616-31-6)

Guidance literature:

diethyl phenylsulfonylmethylphosphonate; With sodium hydride; In tetrahydrofuran; at 0 ℃; for 0.5h; Inert atmosphere;

phenylacetaldehyde; In tetrahydrofuran; for 1h; regioselective reaction; Inert atmosphere;

DOI:10.1016/j.tetlet.2013.03.056

Reference yield:

2-(1-Benzenesulfonyl-3-phenyl-propane-1-sulfinyl)-pyridine → (E)-((3-phenylprop-1-en-1-yl)sulfonyl)benzene (133616-31-6)

Guidance literature:

With hydrogenchloride; at 100 ℃; for 2h; Yield given;

DOI:10.1246/bcsj.64.57

upstream raw materials:

allylbenzene

PVS

benzyl chlorooxalate

2-(1-Benzenesulfonyl-3-phenyl-propylsulfanyl)-pyridine

Refernces

• 1、 Dana, Dibyendu,Davalos, Anibal R.,Subramaniam, Gopal,Afzal, Nisar,Hersh, William H.,Kumar, Sanjai. "A base-controlled regioselective synthesis of allyl and vinyl phenyl sulfones". . p. 2717 - 2721. Retrieved 2013/06/26.
• 2、 Michrowska, Anna,Bieniek, Micha?,Kim, Mikhail,Klajn, Rafa?,Grela, Karol. "Cross-metathesis reaction of vinyl sulfones and sulfoxides". . p. 4525 - 4531. Retrieved 2007/10/03.