2,6-dimethylphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1→6)-3-O-acetyl-4-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

Base Information

Chemical Name:2,6-dimethylphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1→6)-3-O-acetyl-4-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside
CAS No.:1450810-18-0
Molecular Formula:C₅₁H₅₀N₂O₁₆S
Molecular Weight:979.028
Hs Code.:

2,6-dimethylphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1→6)-3-O-acetyl-4-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

Synonyms:2,6-dimethylphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1→6)-3-O-acetyl-4-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

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Chemical Property of 2,6-dimethylphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1→6)-3-O-acetyl-4-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

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Technology Process of 2,6-dimethylphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1→6)-3-O-acetyl-4-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

There total 15 articles about 2,6-dimethylphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1→6)-3-O-acetyl-4-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 10022-13-6
1,3,4,6-tetra-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranose

: 1450810-18-0
2,6-dimethylphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1→6)-3-O-acetyl-4-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: boron trifluoride diethyl etherate / dichloromethane / 0 - 20 °C

2: dichloromethane / -78 °C / Electrolysis

3: dichloromethane / -78 - 0 °C

With boron trifluoride diethyl etherate; In dichloromethane;
DOI:10.1021/ol402034g

Reference yield:

: 1450810-09-9
2,6-Dimethylphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

: 1450810-18-0
2,6-dimethylphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1→6)-3-O-acetyl-4-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: dichloromethane / -78 °C / Electrolysis

2: dichloromethane / -78 - 0 °C

In dichloromethane;
DOI:10.1021/ol402034g

Reference yield:

: 118-72-9
2,6-dimethylbenzene-1-thiol

: 1450810-18-0
2,6-dimethylphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1→6)-3-O-acetyl-4-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: boron trifluoride diethyl etherate / dichloromethane / 0 - 20 °C

2: hydrogenchloride / methanol; diethyl ether / 7 h / 20 °C

3: CSA / methanol; diethyl ether; N,N-dimethyl-formamide / 20 °C

4: dmap; pyridine / 0 - 20 °C

5: borane-THF; trimethylsilyl trifluoromethanesulfonate / 0 °C

6: dichloromethane / -78 - 0 °C

With pyridine; hydrogenchloride; dmap; borane-THF; trimethylsilyl trifluoromethanesulfonate; boron trifluoride diethyl etherate; In methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ol402034g