bis(triphenylphosphoranylidene)ammonium tetrakis(pentafluorophenyl) borate

Base Information

• Chemical Name: bis(triphenylphosphoranylidene)ammonium tetrakis(pentafluorophenyl) borate
• CAS No.: 227603-93-2
• Molecular Formula: C₂₄BF₂₀*C₃₆H₃₀NP₂
• Molecular Weight: 1217.63
• Mol file: 227603-93-2.mol

Synonyms:bis(triphenylphosphoranylidene)ammonium tetrakis(pentafluorophenyl) borate

Chemical Property of bis(triphenylphosphoranylidene)ammonium tetrakis(pentafluorophenyl) borate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of bis(triphenylphosphoranylidene)ammonium tetrakis(pentafluorophenyl) borate

There total 4 articles about bis(triphenylphosphoranylidene)ammonium tetrakis(pentafluorophenyl) borate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

lithium tetrakis(pentafluorophenyl)borate/ethyl ether complex (155543-02-5) + bis(triphenylphosphine)iminium chloride (21050-13-5) → bis(triphenylphosphoranylidene)ammonium tetrakis(pentafluorophenyl) borate (227603-93-2)

Guidance literature:

With tetrakis(4-sulfophenyl)ethene; In methanol; water;

DOI:10.1021/acs.langmuir.0c01962

Reference yield:

C18H3F13P(1+)*C24BF20(1-) → bis(triphenylphosphoranylidene)ammonium tetrakis(pentafluorophenyl) borate (227603-93-2)

Guidance literature:

Multi-step reaction with 3 steps

1: trimethylsilylazide / dichloromethane

2: dichloromethane

3: 3 h / 100 °C

With trimethylsilylazide; In dichloromethane;

DOI:10.1039/c5sc02336j

Reference yield:

bis(triphenylphosphine)iminium chloride (21050-13-5) + lithium tetrakis(pentafluorophenyl)borate (2797-28-6) → bis(triphenylphosphoranylidene)ammonium tetrakis(pentafluorophenyl) borate (227603-93-2)

Guidance literature:

In further solvent(s); further solvent DCE;

DOI:10.1016/j.electacta.2011.12.037

upstream raw materials:

bis(triphenylphosphine)iminium chloride

lithium tetrakis(pentafluorophenyl)borate

lithium tetrakis(pentafluorophenyl)borate/ethyl ether complex