Technology Process of octadecahydro-7-benzyl-1,6-methanocyclopenta<3,4>pentaleno<2,1,6-cde>pentaleno<2,1,6-gha>pentalene-7-methanol
There total 4 articles about octadecahydro-7-benzyl-1,6-methanocyclopenta<3,4>pentaleno<2,1,6-cde>pentaleno<2,1,6-gha>pentalene-7-methanol which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
diisobutylaluminium hydride;
In
benzene;
for 24h;
DOI:10.1021/jo00383a017
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 1.) Li, NH3 / 1.) 1,2-dimethoxyethane, -78 deg C, 30 min, 2.) 1,2-dimethoxyethane, a) -78 deg C, 30 min, b) -33 deg C, 30 min
2: 2.) p-toluenosulfonic acid / 1.) tert-butyl alcohol, benzene, irradiation, 23 h, 2.) benzene, reflux, 5 h
3: 95.1 percent / H2NNH2, 30percent aq. H2O2 / tetrahydrofuran; ethanol / Ambient temperature
4: 96.7 percent / diisobutyl aluminium hydride / benzene / 24 h
With
ammonia; dihydrogen peroxide; lithium; diisobutylaluminium hydride; toluene-4-sulfonic acid; hydrazine;
In
tetrahydrofuran; ethanol; benzene;
DOI:10.1021/jo00383a017
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 2.) p-toluenosulfonic acid / 1.) tert-butyl alcohol, benzene, irradiation, 23 h, 2.) benzene, reflux, 5 h
2: 95.1 percent / H2NNH2, 30percent aq. H2O2 / tetrahydrofuran; ethanol / Ambient temperature
3: 96.7 percent / diisobutyl aluminium hydride / benzene / 24 h
With
dihydrogen peroxide; diisobutylaluminium hydride; toluene-4-sulfonic acid; hydrazine;
In
tetrahydrofuran; ethanol; benzene;
DOI:10.1021/jo00383a017
