(E)-diethyl (2-(o-tolyl)prop-1-en-1-yl)phosphonate

Base Information

Chemical Name:(E)-diethyl (2-(o-tolyl)prop-1-en-1-yl)phosphonate
CAS No.:1200436-16-3
Molecular Formula:C₁₄H₂₁O₃P
Molecular Weight:268.293
Hs Code.:

Synonyms:(E)-diethyl (2-(o-tolyl)prop-1-en-1-yl)phosphonate

Suppliers and Price of (E)-diethyl (2-(o-tolyl)prop-1-en-1-yl)phosphonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (E)-diethyl (2-(o-tolyl)prop-1-en-1-yl)phosphonate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (E)-diethyl (2-(o-tolyl)prop-1-en-1-yl)phosphonate

There total 1 articles about (E)-diethyl (2-(o-tolyl)prop-1-en-1-yl)phosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 1660-94-2
Tetraethyl methylenediphosphonate

: 577-16-2,122382-54-1
2-Methylacetophenone

: 1200436-16-3
(E)-diethyl (2-(o-tolyl)prop-1-en-1-yl)phosphonate

Guidance literature:: Tetraethyl methylenediphosphonate; With sodium hydride; In tetrahydrofuran; mineral oil; at 0 ℃; Schlenk technique; Inert atmosphere;

2-Methylacetophenone; In tetrahydrofuran; mineral oil; at 60 ℃; Schlenk technique; Inert atmosphere;
DOI:10.1002/anie.201911651

Reference yield: 95.0%

: 1200436-16-3
(E)-diethyl (2-(o-tolyl)prop-1-en-1-yl)phosphonate

: diethyl 2-(2-methylphenyl)propylphosphonate

Guidance literature:: With bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; C₄₈H₄₅FeN₃P₂; hydrogen; In dichloromethane; at 20 ℃; for 24h; under 30402 Torr; optical yield given as %ee; enantioselective reaction; Inert atmosphere; Autoclave;
DOI:10.1021/jo300129m

Reference yield: 93.0%

: 1200436-16-3
(E)-diethyl (2-(o-tolyl)prop-1-en-1-yl)phosphonate

: diethyl (R)-(2-(2-tolyl)propyl)phosphonate

Guidance literature:: With bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; (R)-1-{(R)-2-(2'-diphenylphosphinophenyl)ferrocenyl}ethyldi(3,5-xylyl)phosphine; hydrogen; In dichloromethane; at 20 ℃; for 24h; under 7500.75 Torr; enantioselective reaction; Glovebox; Autoclave;
DOI:10.1002/anie.201911651