Bis(1,3-propanediamine) Copper(II) Dichloride

Base Information

• Chemical Name: Bis(1,3-propanediamine) Copper(II) Dichloride
• CAS No.: 32270-93-2
• Molecular Formula: C₆H₂₀Cl₂CuN₄
• Molecular Weight: 282.704
• European Community (EC) Number: 677-998-5
• DSSTox Substance ID: DTXSID50514304
• Mol file: 32270-93-2.mol

Synonyms:Bis(1,3-propanediamine) Copper(II) Dichloride;32270-93-2;dichlorocopper;propane-1,3-diamine;SCHEMBL969892;DTXSID50514304;MFCD00191318;AKOS015833216;Propane-1,3-diamine--dichlorocopper (2/1);bis(1,3-propanediamine)copper(ii) dichloride;D88819

Chemical Property of Bis(1,3-propanediamine) Copper(II) Dichloride

Chemical Property:

• PSA: 104.08000
• LogP: 2.76550
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 281.036099
• Heavy Atom Count: 13
• Complexity: 15.1

Purity/Quality:

98%,99%, ^*data from raw suppliers

Bis(1,3-propanediamine) Copper(II) Dichloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(CN)CN.C(CN)CN.Cl[Cu]Cl

Technology Process of Bis(1,3-propanediamine) Copper(II) Dichloride

There total 2 articles about Bis(1,3-propanediamine) Copper(II) Dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

Trimethylenediamine (109-76-2,54018-94-9) + copper dichloride → chlorodi(1,3-diaminopropane-N,N')copper(II) chloride (15558-15-3,176547-89-0,32270-93-2,770736-33-9,85761-02-0)

Guidance literature:

In tetrahydrofuran; ethanol; pptn on addn. of 2 equiv. ligand (in EtOH) to CuCl2 (in THF/EtOH=5:3 v/v); collection (filtration), washing (Et2O);

DOI:10.1016/0020-1693(95)04796-4

Reference yield: 51.0%

copper(II) choride dihydrate + Trimethylenediamine (109-76-2,54018-94-9) → bis(1,3-propanediamine)copper(II) dichloride (32270-93-2,85761-02-0,176547-89-0,770736-33-9,15558-15-3)

Guidance literature:

In ethanol; soln. CuCl2*2H2O in EtOH was added to EtOH soln. propanediamine at room temp.; crystals were washed with EtOH and Et2O and dried over CaCl2 under vac.;elem. anal.;

DOI:10.1081/SIM-120024322

upstream raw materials:

Trimethylenediamine

Refernces

• 1、 Sundberg, Markku R.,Sillanpaeae, Reijo,Uggla, Rolf. "Conformational flexibility of the di(1,3-diaminopropane)-copper(II) cation: Part 2 1. Structure determination for aqua-di(1,3-diaminopropane-N,N′)-copper(II) dichloride and chlorodi(1,3-diaminopropane-N,N′)-copper(II) chloride methanol solvate and DFT calculations for aqua-di(1,3-diaminopropane-N,N′)copper(II) cation". . p. 35 - 42. Retrieved 2008/10/08.