dicarbonyliodo{η5-(1-phenylborole)}cobalt

Base Information

Chemical Name:dicarbonyliodo{η5-(1-phenylborole)}cobalt
CAS No.:111800-70-5
Molecular Formula:C₁₂H₉BCoIO₂
Molecular Weight:381.911
Hs Code.:

Synonyms:dicarbonyliodo{η5-(1-phenylborole)}cobalt

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of dicarbonyliodo{η5-(1-phenylborole)}cobalt

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Technology Process of dicarbonyliodo{η5-(1-phenylborole)}cobalt

There total 1 articles about dicarbonyliodo{η5-(1-phenylborole)}cobalt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: di-μ-carbonyl-bis{carbonyl(η5-1-phenylborole)cobalt}(Co-Co)

: 111800-70-5
dicarbonyliodo{η5-(1-phenylborole)}cobalt

Guidance literature:: With iodine; In dichloromethane; CH2Cl2 soln. of I2 was added dropwise at -80°C to a soln. of Co-complex in CH2Cl2 under N2, mixt. was allowed to warm to room temp.; concd., Et2O was added, soln. was cooled to -60°C; elem. anal.;
DOI:10.1016/0022-328X(87)80343-1

Reference yield: 10.0%

: 12130-66-4
bis(cycloocta-1,5-diene)platinum⁽⁰⁾

: 111800-70-5
dicarbonyliodo{η5-(1-phenylborole)}cobalt

: 121545-36-6
(η4-1,5-cyclooctadien){η5-(1-phenylborol)}platinum

Guidance literature:: In tetrahydrofuran; byproducts: COD, NH3; under N, 3h at 45-50°C,; evapn., chromy. in pentane/ether on Al2O3, crystn.(pentane or aceton), elem. anal.;
DOI:10.1016/0022-328X(88)80362-0

Reference yield:

: 111800-70-5
dicarbonyliodo{η5-(1-phenylborole)}cobalt

: 117696-62-5
C₄H₄B(C₆H₅)(NH₃)

Guidance literature:: With ammonia; In tetrahydrofuran; byproducts: CO, NH3; addn. of liq. ammonia at -80°C, (ether is possible also as solvent), warming with stirring to room temp.; filtration after gas evolution, washing, in filtrate is the product;
DOI:10.1016/0022-328X(88)80362-0