(+/-)-4c-(toluene-4-sulfonyloxymethyl)-cyclohexane-1r,2t-diol

Base Information

• Chemical Name: (+/-)-4c-(toluene-4-sulfonyloxymethyl)-cyclohexane-1r,2t-diol
• CAS No.: 106477-19-4
• Molecular Formula: C₁₄H₂₀O₅S
• Molecular Weight: 300.376
• Mol file: 106477-19-4.mol

Synonyms:(+/-)-4c-(toluene-4-sulfonyloxymethyl)-cyclohexane-1r,2t-diol

Chemical Property of (+/-)-4c-(toluene-4-sulfonyloxymethyl)-cyclohexane-1r,2t-diol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (+/-)-4c-(toluene-4-sulfonyloxymethyl)-cyclohexane-1r,2t-diol

There total 4 articles about (+/-)-4c-(toluene-4-sulfonyloxymethyl)-cyclohexane-1r,2t-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(+/-)-3t,4c-dihydroxy-cyclohexane-r-carboxylic acid (23477-88-5,31540-11-1,32746-99-9,50426-47-6,67068-73-9,67068-74-0,76704-84-2,333364-12-8) → (+/-)-4c-(toluene-4-sulfonyloxymethyl)-cyclohexane-1r,2t-diol (106477-19-4)

Guidance literature:

Multi-step reaction with 3 steps

2: LiAlH₄; diethyl ether

With lithium aluminium tetrahydride; diethyl ether;

Reference yield:

1,2,5,6-tetrahydrobenzoic acid (4771-80-6) → (+/-)-4c-(toluene-4-sulfonyloxymethyl)-cyclohexane-1r,2t-diol (106477-19-4)

Guidance literature:

Multi-step reaction with 4 steps

1: aqueous peroxyformic acid

3: LiAlH₄; diethyl ether

With lithium aluminium tetrahydride; diethyl ether; Peroxyformic acid;

Reference yield:

(+/-)-3t,4c-dihydroxy-cyclohexane-r-carboxylic acid methyl ester (23266-26-4,127233-08-3,127233-24-3) → (+/-)-4c-(toluene-4-sulfonyloxymethyl)-cyclohexane-1r,2t-diol (106477-19-4)

Guidance literature:

Multi-step reaction with 2 steps

1: LiAlH₄; diethyl ether

With lithium aluminium tetrahydride; diethyl ether;

upstream raw materials:

(+/-)-4c-hydroxymethyl-cyclohexane-1r,2t-diol

p-toluenesulfonyl chloride

1,2,5,6-tetrahydrobenzoic acid

(+/-)-3t,4c-dihydroxy-cyclohexane-r-carboxylic acid