methyl-2,3,4-tetra-O-benzyl-L-glycero-α-D-manno-heptopyranoside

Base Information

• Chemical Name: methyl-2,3,4-tetra-O-benzyl-L-glycero-α-D-manno-heptopyranoside
• CAS No.: 122588-51-6
• Molecular Formula: C₂₉H₃₄O₇
• Molecular Weight: 494.585
• Mol file: 122588-51-6.mol

Synonyms:methyl-2,3,4-tetra-O-benzyl-L-glycero-α-D-manno-heptopyranoside

Chemical Property of methyl-2,3,4-tetra-O-benzyl-L-glycero-α-D-manno-heptopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl-2,3,4-tetra-O-benzyl-L-glycero-α-D-manno-heptopyranoside

There total 14 articles about methyl-2,3,4-tetra-O-benzyl-L-glycero-α-D-manno-heptopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

methyl 6-O-anilino-2,3,4-tri-O-benzyl-L-glycero-α-D-manno-heptopyranoside → methyl-2,3,4-tetra-O-benzyl-L-glycero-α-D-manno-heptopyranoside (122588-51-6)

Guidance literature:

With copper(II) sulfate; In methanol; at 0 ℃; for 18h;

DOI:10.1021/acs.orglett.5b02620

Reference yield: 85.0%

methyl-2,3,4-tri-O-benzyl-7-(Si-dimethylphenyl-silyl)-L-glycero-α-Dmanno-heptopyranoside (122588-55-0) → methyl-2,3,4-tetra-O-benzyl-L-glycero-α-D-manno-heptopyranoside (122588-51-6)

Guidance literature:

With peracetic acid; sodium acetate; sodium bromide;

DOI:10.1016/S0040-4039(00)95167-0

Reference yield: 66.0%

methyl 7-O-allyl-2,3,4-tri-O-benzyl-L-glycero-α-D-manno-heptopyranoside (211231-29-7) → methyl-2,3,4-tetra-O-benzyl-L-glycero-α-D-manno-heptopyranoside (122588-51-6)

Guidance literature:

With palladium dichloride; In methanol; ethanol;

DOI:10.1016/S0008-6215(98)00271-7

upstream raw materials:

(R)-2-(Isopropoxy-dimethyl-silanyl)-1-((2R,3S,4S,5S,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-ethanol

methyl-2,3,4-tri-O-benzyl-7-(Si-dimethylphenyl-silyl)-L-glycero-α-Dmanno-heptopyranoside

methyl (6R)-2,3,4-tri-O-benzyl-6-(2-thiazolyl)-α-D-mannopyranoside

methyl 7-O-allyl-2,3,4-tri-O-benzyl-L-glycero-α-D-manno-heptopyranoside

Downstream raw materials:

methyl 6,7-di-O-acetyl-2,3,4-tri-O-benzyl-L-glycero-α-D-manno-heptopyranoside

methyl L-glycero-α-D-manno-heptopyranoside

(2R,3S,4S,5S,6S)-3,4,5-Tris-benzyloxy-2-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-6-methoxy-tetrahydro-pyran

methyl 2,3,4-tri-O-benzyl-7-O-tert-butyldimethylsilyl-L-glycero-α-D-manno-heptopyranoside