<6S,4R(1'S,2'R)>-6-hydroxy-4-<1'-(3'-O-p-nitrobenzoyl-1',2',3'-trihydroxypropyl)>-N-tryptophyl-2-piperidone-2'-6-anhydro

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Chemical Name:<6S,4R(1'S,2'R)>-6-hydroxy-4-<1'-(3'-O-p-nitrobenzoyl-1',2',3'-trihydroxypropyl)>-N-tryptophyl-2-piperidone-2'-6-anhydro
CAS No.:138704-20-8
Molecular Formula:C₂₅H₂₅N₃O₇
Molecular Weight:479.489
Hs Code.:

Synonyms:<6S,4R(1'S,2'R)>-6-hydroxy-4-<1'-(3'-O-p-nitrobenzoyl-1',2',3'-trihydroxypropyl)>-N-tryptophyl-2-piperidone-2'-6-anhydro

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Chemical Property of <6S,4R(1'S,2'R)>-6-hydroxy-4-<1'-(3'-O-p-nitrobenzoyl-1',2',3'-trihydroxypropyl)>-N-tryptophyl-2-piperidone-2'-6-anhydro

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Technology Process of <6S,4R(1'S,2'R)>-6-hydroxy-4-<1'-(3'-O-p-nitrobenzoyl-1',2',3'-trihydroxypropyl)>-N-tryptophyl-2-piperidone-2'-6-anhydro

There total 6 articles about <6S,4R(1'S,2'R)>-6-hydroxy-4-<1'-(3'-O-p-nitrobenzoyl-1',2',3'-trihydroxypropyl)>-N-tryptophyl-2-piperidone-2'-6-anhydro which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 61-54-1
tryptamine

: 213969-31-4
6-O-p-nitrobenzoyl-3-C-(carboxymethylene)-2,3-didesoxy-α-β-D-ribo-hexapyranose-2,4-γ-lactone

: 138704-20-8
<6S,4R(1'S,2'R)>-6-hydroxy-4-<1'-(3'-O-p-nitrobenzoyl-1',2',3'-trihydroxypropyl)>-N-tryptophyl-2-piperidone-2'-6-anhydro

Guidance literature:: With acetic acid; In benzene; for 2h; Heating;
DOI:10.1016/S0040-4039(00)92154-3

Reference yield:

: 88901-92-2
methyl 4,6-O-benzylidene-3-C-(carbomethoxy-methylene)-2,3-didesoxy-α-D-ribo-hexapyranoside

: 138704-20-8
<6S,4R(1'S,2'R)>-6-hydroxy-4-<1'-(3'-O-p-nitrobenzoyl-1',2',3'-trihydroxypropyl)>-N-tryptophyl-2-piperidone-2'-6-anhydro

Guidance literature:: Multi-step reaction with 4 steps

1: 80 percent / hydrogen / 10percent Pd-C / methanol / 12 h

2: 80 percent / pyridine / 20 deg C, 24 h, then 70 deg C, 1 h

3: 87 percent / acetic acid, water / 12 h / Heating

4: 85 percent / acetic acid / benzene / 2 h / Heating

With pyridine; water; hydrogen; acetic acid; palladium on activated charcoal; In methanol; benzene;
DOI:10.1016/S0040-4020(01)80014-4

Reference yield:

: 134747-17-4
methyl 3-C-(carboxymethylene)-2,3-didesoxy-α-D-ribo-hexapyranoside-2',4-γ-lactone

: 138704-20-8
<6S,4R(1'S,2'R)>-6-hydroxy-4-<1'-(3'-O-p-nitrobenzoyl-1',2',3'-trihydroxypropyl)>-N-tryptophyl-2-piperidone-2'-6-anhydro

Guidance literature:: Multi-step reaction with 3 steps

1: 80 percent / pyridine / 20 deg C, 24 h, then 70 deg C, 1 h

2: 87 percent / acetic acid, water / 12 h / Heating

3: 85 percent / acetic acid / benzene / 2 h / Heating

With pyridine; water; acetic acid; In benzene;
DOI:10.1016/S0040-4020(01)80014-4