(E)-4-(N-allyl-4-methylphenylsulfonamido)but-3-en-2-yl 2-(benzo[d][1,3]dioxol-5-yl)acetate

Base Information

Chemical Name:(E)-4-(N-allyl-4-methylphenylsulfonamido)but-3-en-2-yl 2-(benzo[d][1,3]dioxol-5-yl)acetate
CAS No.:1357059-30-3
Molecular Formula:C₂₃H₂₅NO₆S
Molecular Weight:443.521
Hs Code.:

Synonyms:(E)-4-(N-allyl-4-methylphenylsulfonamido)but-3-en-2-yl 2-(benzo[d][1,3]dioxol-5-yl)acetate

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Chemical Property of (E)-4-(N-allyl-4-methylphenylsulfonamido)but-3-en-2-yl 2-(benzo[d][1,3]dioxol-5-yl)acetate

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Technology Process of (E)-4-(N-allyl-4-methylphenylsulfonamido)but-3-en-2-yl 2-(benzo[d][1,3]dioxol-5-yl)acetate

There total 2 articles about (E)-4-(N-allyl-4-methylphenylsulfonamido)but-3-en-2-yl 2-(benzo[d][1,3]dioxol-5-yl)acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 2861-28-1
1,3-benzodioxole-5-acetic acid

: 1357059-20-1
(E)-N-allyl-N-(3-hydroxybut-1-enyl)-4-methylbenzenesulfonamide

: 1357059-30-3
(E)-4-(N-allyl-4-methylphenylsulfonamido)but-3-en-2-yl 2-(benzo[d][1,3]dioxol-5-yl)acetate

Guidance literature:: With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; In dichloromethane; at 0 - 20 ℃; for 15h; Inert atmosphere;
DOI:10.1039/c2ob06853b

Reference yield:

: 1357059-18-7
(E)-N-allyl-4-N-(3-oxobut-1-enyl)-4-methylbenzenesulfonamide

: 1357059-30-3
(E)-4-(N-allyl-4-methylphenylsulfonamido)but-3-en-2-yl 2-(benzo[d][1,3]dioxol-5-yl)acetate

Guidance literature:: Multi-step reaction with 2 steps

1: sodium tetrahydroborate / tetrahydrofuran; methanol / 12 h / 0 - 20 °C / Inert atmosphere

2: dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine / dichloromethane / 15 h / 0 - 20 °C / Inert atmosphere

With dmap; sodium tetrahydroborate; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1039/c2ob06853b

Reference yield:

: 1357059-30-3
(E)-4-(N-allyl-4-methylphenylsulfonamido)but-3-en-2-yl 2-(benzo[d][1,3]dioxol-5-yl)acetate

: C₂₃H₂₅NO₆S

Guidance literature:: With chloro-trimethyl-silane; lithium hexamethyldisilazane; In tetrahydrofuran; toluene; at -95 - 20 ℃; for 1.25h; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1039/c2ob06853b