C₄₄H₅₈O₉Si

Base Information

Chemical Name:C₄₄H₅₈O₉Si
CAS No.:872525-95-6
Molecular Formula:C₄₄H₅₈O₉Si
Molecular Weight:759.025
Hs Code.:

C<sub>44</sub>H<sub>58</sub>O<sub>9</sub>Si

Synonyms:C₄₄H₅₈O₉Si

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Chemical Property of C₄₄H₅₈O₉Si

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Technology Process of C₄₄H₅₈O₉Si

There total 20 articles about C₄₄H₅₈O₉Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 872525-94-5
C₅₀H₆₄O₉SeSi

: 872525-95-6
C₄₄H₅₈O₉Si

Guidance literature:: With dihydrogen peroxide; In dichloromethane; at 20 ℃; for 1h;
DOI:10.1139/v05-042

Reference yield:

: 872525-98-9
(3aR,7aS)-2,2-Dimethyl-6-oxo-3a,6,7,7a-tetrahydro-benzo[1,3]dioxole-5-carbaldehyde

: 872525-95-6
C₄₄H₅₈O₉Si

Guidance literature:: Multi-step reaction with 11 steps

1: 77 percent / cesium carbonate / CH₂Cl₂ / 2 h / 20 °C

2: 86 percent / morpholine / tetrakis(triphenylphosphine)palladium⁽⁰⁾ / tetrahydrofuran / 0.08 h / 20 °C

3: 99 percent / LiAlH[OC(C₂H₅)3]3 / tetrahydrofuran / 1 h / 0 °C

4: 71 percent / diisopropylethylamine / CH₂Cl₂ / 16 h / 20 °C

5: 28 percent / potassium hexamethyldisilazide / tetrahydrofuran; toluene / 0.5 h / Heating

6: 96 percent / Ne₄NHB(OAc)3; acetic acid / acetonitrile / 19 h / -20 - 0 °C

7: 93 percent / camphorsulfonic acid / acetone / 1 h / 20 °C

8: 86 percent / potassium hexamethyldisilazide / tetrahydrofuran; toluene / 0.33 h / Heating

9: 100 percent Turnov_. / triethylamine / CH₂Cl₂ / 3 h / 20 °C

10: 71 percent / 2,6-di-tert-butylpyridine / CH₂Cl₂ / 9 h / 20 °C

11: 57 percent / hydrogen peroxide / CH₂Cl₂ / 1 h / 20 °C

With morpholine; 2,6-di-tert-butyl-pyridine; lithium tris[(3-ethyl-3-pentyl)oxy]aluminohydride; Ne₄NHB(OAc)3; camphor-10-sulfonic acid; dihydrogen peroxide; potassium hexamethylsilazane; caesium carbonate; acetic acid; triethylamine; N-ethyl-N,N-diisopropylamine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; dichloromethane; acetone; toluene; acetonitrile; 5: aldol condensation / 8: aldol condensation;
DOI:10.1139/v05-042

Reference yield:

: 872525-77-4
2-(5-formyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-N-methoxy-N-methyl-acetamide

: 872525-95-6
C₄₄H₅₈O₉Si

Guidance literature:: Multi-step reaction with 16 steps

1.1: 3.00 g / tetrahydrofuran; toluene / 1 h / 0 °C

2.1: 92 percent / diisobutylaluminum hydride / tetrahydrofuran; toluene / 1 h / -78 °C

3.1: t-butyllithium / diethyl ether; pentane / 4 h / 0 °C

3.2: 98 percent / diethyl ether; pentane / 0.5 h / 0 °C

4.1: 73 percent / Grubb's second generation catalyst / CH₂Cl₂ / 40 °C

5.1: 80 percent / Dess-Martin periodinane / CH₂Cl₂ / 1 h / 20 °C

6.1: 77 percent / cesium carbonate / CH₂Cl₂ / 2 h / 20 °C

7.1: 86 percent / morpholine / tetrakis(triphenylphosphine)palladium⁽⁰⁾ / tetrahydrofuran / 0.08 h / 20 °C

8.1: 99 percent / LiAlH[OC(C₂H₅)3]3 / tetrahydrofuran / 1 h / 0 °C

9.1: 71 percent / diisopropylethylamine / CH₂Cl₂ / 16 h / 20 °C

10.1: 28 percent / potassium hexamethyldisilazide / tetrahydrofuran; toluene / 0.5 h / Heating

11.1: 96 percent / Ne₄NHB(OAc)3; acetic acid / acetonitrile / 19 h / -20 - 0 °C

12.1: 93 percent / camphorsulfonic acid / acetone / 1 h / 20 °C

13.1: 86 percent / potassium hexamethyldisilazide / tetrahydrofuran; toluene / 0.33 h / Heating

14.1: 100 percent Turnov_. / triethylamine / CH₂Cl₂ / 3 h / 20 °C

15.1: 71 percent / 2,6-di-tert-butylpyridine / CH₂Cl₂ / 9 h / 20 °C

16.1: 57 percent / hydrogen peroxide / CH₂Cl₂ / 1 h / 20 °C

With morpholine; 2,6-di-tert-butyl-pyridine; lithium tris[(3-ethyl-3-pentyl)oxy]aluminohydride; Ne₄NHB(OAc)3; camphor-10-sulfonic acid; dihydrogen peroxide; tert.-butyl lithium; potassium hexamethylsilazane; diisobutylaluminium hydride; caesium carbonate; Dess-Martin periodane; acetic acid; triethylamine; N-ethyl-N,N-diisopropylamine; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; diethyl ether; dichloromethane; acetone; toluene; acetonitrile; pentane; 1.1: Wittig reaction / 10.1: aldol condensation / 13.1: aldol condensation;
DOI:10.1139/v05-042