[{3,5-dimethyl-2,6-bis(1-(2,6-dimethyl-4-(thiophen-2-yl)phenyl)-1H-1,2,3-triazol-4-yl)benzene}{2,2':6',2-terpyridine}ruthenium(II)]hexafluorophosphate

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Chemical Name:[{3,5-dimethyl-2,6-bis(1-(2,6-dimethyl-4-(thiophen-2-yl)phenyl)-1H-1,2,3-triazol-4-yl)benzene}{2,2':6',2-terpyridine}ruthenium(II)]hexafluorophosphate
CAS No.:1579992-69-0
Molecular Formula:C₅₁H₄₂N₉RuS₂*F₆P
Molecular Weight:1091.12
Hs Code.:

Synonyms:[{3,5-dimethyl-2,6-bis(1-(2,6-dimethyl-4-(thiophen-2-yl)phenyl)-1H-1,2,3-triazol-4-yl)benzene}{2,2':6',2-terpyridine}ruthenium(II)]hexafluorophosphate

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Chemical Property of [{3,5-dimethyl-2,6-bis(1-(2,6-dimethyl-4-(thiophen-2-yl)phenyl)-1H-1,2,3-triazol-4-yl)benzene}{2,2':6',2-terpyridine}ruthenium(II)]hexafluorophosphate

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Technology Process of [{3,5-dimethyl-2,6-bis(1-(2,6-dimethyl-4-(thiophen-2-yl)phenyl)-1H-1,2,3-triazol-4-yl)benzene}{2,2':6',2-terpyridine}ruthenium(II)]hexafluorophosphate

There total 2 articles about [{3,5-dimethyl-2,6-bis(1-(2,6-dimethyl-4-(thiophen-2-yl)phenyl)-1H-1,2,3-triazol-4-yl)benzene}{2,2':6',2-terpyridine}ruthenium(II)]hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1227043-55-1
2-azido-5-bromo-1,3-dimethylbenzene

: 1579992-69-0
[{3,5-dimethyl-2,6-bis(1-(2,6-dimethyl-4-(thiophen-2-yl)phenyl)-1H-1,2,3-triazol-4-yl)benzene}{2,2':6',2-terpyridine}ruthenium(II)]hexafluorophosphate

Guidance literature:: Multi-step reaction with 3 steps

1: potassium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾ / N,N-dimethyl-formamide / 12 h / 50 °C / Inert atmosphere; Darkness

2: (+)-sodium L-ascorbate; copper(II) sulfate / dichloromethane; ethanol; water / 12 h / 50 °C / Darkness

3: ethanol; toluene / 2 h / 140 °C / Inert atmosphere; Microwave irradiation

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; (+)-sodium L-ascorbate; potassium carbonate; copper(II) sulfate; In ethanol; dichloromethane; water; N,N-dimethyl-formamide; toluene; 1: |Suzuki Coupling;
DOI:10.1002/chem.201301439

Reference yield:

: 2-(4-azido-3,5-dimethylphenyl)thiophene

: 1579992-69-0
[{3,5-dimethyl-2,6-bis(1-(2,6-dimethyl-4-(thiophen-2-yl)phenyl)-1H-1,2,3-triazol-4-yl)benzene}{2,2':6',2-terpyridine}ruthenium(II)]hexafluorophosphate

Guidance literature:: Multi-step reaction with 2 steps

1: (+)-sodium L-ascorbate; copper(II) sulfate / dichloromethane; ethanol; water / 12 h / 50 °C / Darkness

2: ethanol; toluene / 2 h / 140 °C / Inert atmosphere; Microwave irradiation

With (+)-sodium L-ascorbate; copper(II) sulfate; In ethanol; dichloromethane; water; toluene;
DOI:10.1002/chem.201301439