(η5-pentaphenylcyclopentadienyl)(η3-2-chloroallyl)palladium(II)

Base Information

Chemical Name:(η5-pentaphenylcyclopentadienyl)(η3-2-chloroallyl)palladium(II)
CAS No.:87183-84-4
Molecular Formula:C₃₈H₂₉ClPd
Molecular Weight:627.521
Hs Code.:

Synonyms:(η5-pentaphenylcyclopentadienyl)(η3-2-chloroallyl)palladium(II)

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Chemical Property of (η5-pentaphenylcyclopentadienyl)(η3-2-chloroallyl)palladium(II)

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Technology Process of (η5-pentaphenylcyclopentadienyl)(η3-2-chloroallyl)palladium(II)

There total 1 articles about (η5-pentaphenylcyclopentadienyl)(η3-2-chloroallyl)palladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: bis(μ-chloro)-bis(η(3)-2-chloro-propenyl)palladium

: 5724-11-8
5-chloro-1,2,3,4,5-pentaphenylcyclopentadiene

: 87183-84-4
(η5-pentaphenylcyclopentadienyl)(η3-2-chloroallyl)palladium(II)

Guidance literature:: With sodium amalgam; In tetrahydrofuran; byproducts: sodium chloride; under N2, soln. of Ph5C5Cl in THF added to Na/Hg in THF, supernatant transferred to soln. of (C3H4Cl)2Cl2Pd2 in THF, extd. with THF, soln. stirred 30 min; solvent removed in vac., extd. with CH2Cl2, filtered, evapd. to dryness under reduced pressure, recrystd. from CH2Cl2-MeOH; elem. anal.;
DOI:10.1021/om50006a007

Reference yield: 95.0%

: 87183-84-4
(η5-pentaphenylcyclopentadienyl)(η3-2-chloroallyl)palladium(II)

: 63946-67-8
bis(μ-chloro)bis(η5-pentaphenylcyclopentadienyl)dipalladium(II)

Guidance literature:: In neat (no solvent); pyrolysis in vac. at 0.005-0.1 mm Hg (bath temp. 174-176°C); elem. anal.;
DOI:10.1021/om50006a007

Reference yield: 30.0%

: 87183-84-4
(η5-pentaphenylcyclopentadienyl)(η3-2-chloroallyl)palladium(II)

: 594-09-2
trimethylphosphane

: 87183-93-5
(η5-pentaphenylcyclopentadienyl)chloropalladium(II) trimethylphosphine

Guidance literature:: In chloroform; under N2, Me3P added to a soln. of the Pd complex in CHCl3, mixt. refluxed overnight at 70°C; solvent removed under reduced pressure, chromd. (SiO2, benzene, chloroform), evapn. of the chloroform eluate, hexane added; elem. anal.;
DOI:10.1021/om50006a007