benzoic acid 1-[5-(1-benzyloxy-2-hydroxy-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-allyl ester

Base Information

Chemical Name:benzoic acid 1-[5-(1-benzyloxy-2-hydroxy-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-allyl ester
CAS No.:925545-49-9
Molecular Formula:C₂₄H₂₈O₆
Molecular Weight:412.483
Hs Code.:

Synonyms:benzoic acid 1-[5-(1-benzyloxy-2-hydroxy-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-allyl ester

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Chemical Property of benzoic acid 1-[5-(1-benzyloxy-2-hydroxy-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-allyl ester

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Technology Process of benzoic acid 1-[5-(1-benzyloxy-2-hydroxy-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-allyl ester

There total 7 articles about benzoic acid 1-[5-(1-benzyloxy-2-hydroxy-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-allyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: benzoic acid 1-{5-[1-benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-allyl ester

: 925545-49-9
benzoic acid 1-[5-(1-benzyloxy-2-hydroxy-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-allyl ester

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 20 ℃; for 3h;
DOI:10.1021/ol062621o

Reference yield:

: 881302-89-2
1-(2,2,2',2'-tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-prop-2-en-1-ol

: 925545-49-9
benzoic acid 1-[5-(1-benzyloxy-2-hydroxy-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-allyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: pyridine; 4-(dimethylamino)pyridine / CH₂Cl₂ / 20 °C

2: 535 mg / AcOH / H₂O / 11 h / 20 °C

3: imidazole / CH₂Cl₂ / 2 h / 20 °C

4: trifluoromethanesulfonic acid / cyclohexane; CH₂Cl₂ / 3.5 h / 0 - 20 °C

5: 324 mg / TBAF / tetrahydrofuran / 3 h / 20 °C

With pyridine; 1H-imidazole; dmap; trifluorormethanesulfonic acid; tetrabutyl ammonium fluoride; acetic acid; In tetrahydrofuran; dichloromethane; cyclohexane; water;
DOI:10.1021/ol062621o

Reference yield:

: 925545-45-5
benzoic acid 1-[5-(1,2-dihydroxy-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-allyl ester

: 925545-49-9
benzoic acid 1-[5-(1-benzyloxy-2-hydroxy-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-allyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: imidazole / CH₂Cl₂ / 2 h / 20 °C

2: trifluoromethanesulfonic acid / cyclohexane; CH₂Cl₂ / 3.5 h / 0 - 20 °C

3: 324 mg / TBAF / tetrahydrofuran / 3 h / 20 °C

With 1H-imidazole; trifluorormethanesulfonic acid; tetrabutyl ammonium fluoride; In tetrahydrofuran; dichloromethane; cyclohexane;
DOI:10.1021/ol062621o