Ethyl 1-[(diethoxyphosphoryl)sulfanyl]-2-oxocyclohexanecarboxylate

Base Information

• Chemical Name: Ethyl 1-[(diethoxyphosphoryl)sulfanyl]-2-oxocyclohexanecarboxylate
• CAS No.: 533929-11-2
• Molecular Formula: C₁₃H₂₃O₆PS
• Molecular Weight: 338.362
• Mol file: 533929-11-2.mol

Synonyms:Ethyl 1-[(diethoxyphosphoryl)sulfanyl]-2-oxocyclohexanecarboxylate

Chemical Property of Ethyl 1-[(diethoxyphosphoryl)sulfanyl]-2-oxocyclohexanecarboxylate

Chemical Property:

Purity/Quality:

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Technology Process of Ethyl 1-[(diethoxyphosphoryl)sulfanyl]-2-oxocyclohexanecarboxylate

There total 1 articles about Ethyl 1-[(diethoxyphosphoryl)sulfanyl]-2-oxocyclohexanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

diethoxyoxophosphoranesulfenyl chloride (1186-08-9) + ethyl 2-oxocyclohexane carboxylate (1655-07-8) → Ethyl 1-[(diethoxyphosphoryl)sulfanyl]-2-oxocyclohexanecarboxylate (533929-11-2)

Guidance literature:

ethyl 2-oxocyclohexane carboxylate; With sodium hydride; In tetrahydrofuran; at 0 ℃; for 0.5h;

diethoxyoxophosphoranesulfenyl chloride; In tetrahydrofuran; at -78 ℃; for 0.333333h; Further stages.;

DOI:10.1039/b207700k

Reference yield: 90.0%

Ethyl 1-[(diethoxyphosphoryl)sulfanyl]-2-oxocyclohexanecarboxylate (533929-11-2) → Bis{[1-carboethoxy-2-(diethoxyphosphoryl)oxy]cyclohexan-1-yl} disulfide

Guidance literature:

Ethyl 1-[(diethoxyphosphoryl)sulfanyl]-2-oxocyclohexanecarboxylate; With sodium tetrahydroborate; In 1,2-dimethoxyethane; at -78 ℃; for 1.5h;

With iodine; In 1,2-dimethoxyethane; toluene; at -78 - 20 ℃; for 6h; Further stages.;

DOI:10.1039/b207700k

Reference yield: 89.0%

Ethyl 1-[(diethoxyphosphoryl)sulfanyl]-2-oxocyclohexanecarboxylate (533929-11-2) → cyclohex-1-enecarboxylic acid ethyl ester (1617-22-7) + Ethyl 2-[(diethoxyphosphoryl)oxy]-1-sulfanylcyclohexanecarboxylate

Guidance literature:

With sodium tetrahydroborate; In methanol; dichloromethane; at -78 ℃; for 3h;

DOI:10.1039/b207700k

upstream raw materials:

diethoxyoxophosphoranesulfenyl chloride

ethyl 2-oxocyclohexane carboxylate

Downstream raw materials:

cyclohex-1-enecarboxylic acid ethyl ester