2-((3E,6E,9E,12R,14S)-12-((tert-butyldimethylsilyl)oxy)-14-((R,E)-2-((tertbutyldimethylsilyl)oxy)-5-methyl-7-phenylhept-5-en-1-yl)-10-methyl-2-oxooxacyclotetradeca-3,6,9-trien-4-yl)acetic acid

Base Information

Chemical Name:2-((3E,6E,9E,12R,14S)-12-((tert-butyldimethylsilyl)oxy)-14-((R,E)-2-((tertbutyldimethylsilyl)oxy)-5-methyl-7-phenylhept-5-en-1-yl)-10-methyl-2-oxooxacyclotetradeca-3,6,9-trien-4-yl)acetic acid
CAS No.:1375950-94-9
Molecular Formula:C₄₂H₆₈O₆Si₂
Molecular Weight:725.169
Hs Code.:

2-((3E,6E,9E,12R,14S)-12-((tert-butyldimethylsilyl)oxy)-14-((R,E)-2-((tertbutyldimethylsilyl)oxy)-5-methyl-7-phenylhept-5-en-1-yl)-10-methyl-2-oxooxacyclotetradeca-3,6,9-trien-4-yl)acetic acid

Synonyms:2-((3E,6E,9E,12R,14S)-12-((tert-butyldimethylsilyl)oxy)-14-((R,E)-2-((tertbutyldimethylsilyl)oxy)-5-methyl-7-phenylhept-5-en-1-yl)-10-methyl-2-oxooxacyclotetradeca-3,6,9-trien-4-yl)acetic acid

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Chemical Property of 2-((3E,6E,9E,12R,14S)-12-((tert-butyldimethylsilyl)oxy)-14-((R,E)-2-((tertbutyldimethylsilyl)oxy)-5-methyl-7-phenylhept-5-en-1-yl)-10-methyl-2-oxooxacyclotetradeca-3,6,9-trien-4-yl)acetic acid

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Technology Process of 2-((3E,6E,9E,12R,14S)-12-((tert-butyldimethylsilyl)oxy)-14-((R,E)-2-((tertbutyldimethylsilyl)oxy)-5-methyl-7-phenylhept-5-en-1-yl)-10-methyl-2-oxooxacyclotetradeca-3,6,9-trien-4-yl)acetic acid

There total 40 articles about 2-((3E,6E,9E,12R,14S)-12-((tert-butyldimethylsilyl)oxy)-14-((R,E)-2-((tertbutyldimethylsilyl)oxy)-5-methyl-7-phenylhept-5-en-1-yl)-10-methyl-2-oxooxacyclotetradeca-3,6,9-trien-4-yl)acetic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1375950-83-6
(3E,6E,9E,12R,14S)-12-((tert-butyldimethylsilyl)oxy)-14-((R,E)-2-((tert-butyldimethylsilyl)oxy)-5-methyl-7-phenylhept-5-en-1-yl)-4-(2-hydroxyethyl)-10-methyloxacyclotetradeca-3,6,9-trien-2-one

: 1375950-94-9
2-((3E,6E,9E,12R,14S)-12-((tert-butyldimethylsilyl)oxy)-14-((R,E)-2-((tertbutyldimethylsilyl)oxy)-5-methyl-7-phenylhept-5-en-1-yl)-10-methyl-2-oxooxacyclotetradeca-3,6,9-trien-4-yl)acetic acid

Guidance literature:: Multi-step reaction with 2 steps

1: Dess-Martin periodane / dichloromethane / 0 °C

2: sodium dihydrogenphosphate; sodium chlorite; 2,3-Dimethyl-2-butene / dimethyl sulfoxide; tert-butyl alcohol / 0 °C

With sodium chlorite; sodium dihydrogenphosphate; 2,3-Dimethyl-2-butene; Dess-Martin periodane; In dichloromethane; dimethyl sulfoxide; tert-butyl alcohol; 2: Pinnick oxidation;
DOI:10.1002/anie.201108749

Reference yield:

: 1375950-93-8
C₄₂H₆₈O₅Si₂

: 1375950-94-9
2-((3E,6E,9E,12R,14S)-12-((tert-butyldimethylsilyl)oxy)-14-((R,E)-2-((tertbutyldimethylsilyl)oxy)-5-methyl-7-phenylhept-5-en-1-yl)-10-methyl-2-oxooxacyclotetradeca-3,6,9-trien-4-yl)acetic acid

Guidance literature:: With sodium chlorite; sodium dihydrogenphosphate; 2,3-Dimethyl-2-butene; In dimethyl sulfoxide; tert-butyl alcohol; at 0 ℃;
DOI:10.1002/anie.201108749

Reference yield:

: 1375950-92-7
(3E,6E,9E,12R,14S)-12-((tert-butyldimethylsilyl)oxy)-14-((R,E)-2-((tert-butyldimethylsilyl)oxy)-5-methyl-7-phenylhept-5-en-1-yl)-4-(2-((tert-butyldimethylsilyl)oxy)ethyl)-10-methyloxacyclotetradeca-3,6,9-trien-2-one

: 1375950-94-9
2-((3E,6E,9E,12R,14S)-12-((tert-butyldimethylsilyl)oxy)-14-((R,E)-2-((tertbutyldimethylsilyl)oxy)-5-methyl-7-phenylhept-5-en-1-yl)-10-methyl-2-oxooxacyclotetradeca-3,6,9-trien-4-yl)acetic acid

Guidance literature:: Multi-step reaction with 3 steps

1: pyridinium p-toluenesulfonate / methanol / 20 °C

2: Dess-Martin periodane / dichloromethane / 0 °C

3: sodium dihydrogenphosphate; sodium chlorite; 2,3-Dimethyl-2-butene / dimethyl sulfoxide; tert-butyl alcohol / 0 °C

With sodium chlorite; sodium dihydrogenphosphate; 2,3-Dimethyl-2-butene; pyridinium p-toluenesulfonate; Dess-Martin periodane; In methanol; dichloromethane; dimethyl sulfoxide; tert-butyl alcohol; 3: Pinnick oxidation;
DOI:10.1002/anie.201108749