cis-bis(tert-butylacetylide)bis(diphenyl(tert-butylethynyl)phosphine)platinum

Base Information

Chemical Name:cis-bis(tert-butylacetylide)bis(diphenyl(tert-butylethynyl)phosphine)platinum
CAS No.:199740-16-4
Molecular Formula:C₄₈H₅₆P₂Pt
Molecular Weight:890
Hs Code.:

Synonyms:cis-bis(tert-butylacetylide)bis(diphenyl(tert-butylethynyl)phosphine)platinum

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Chemical Property of cis-bis(tert-butylacetylide)bis(diphenyl(tert-butylethynyl)phosphine)platinum

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Technology Process of cis-bis(tert-butylacetylide)bis(diphenyl(tert-butylethynyl)phosphine)platinum

There total 1 articles about cis-bis(tert-butylacetylide)bis(diphenyl(tert-butylethynyl)phosphine)platinum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: Pt(tert-butylacetylide)2(COD)

: 33730-51-7
(3,3-dimethyl-1-butynyl)diphenylphosphine

: 199740-16-4
cis-bis(tert-butylacetylide)bis(diphenyl(tert-butylethynyl)phosphine)platinum

Guidance literature:: In dichloromethane; byproducts: COD; N2-atmosphere; addn. of 2 equivs. of ligand to suspension of Pt-complex,stirring for 10 min; evapn., addn. of iPrOH; elem. anal.;
DOI:10.1021/om970663y

Reference yield: 68.0%

: cis-[(pentafluorophenyl)2 (tetrahydrofurane)2 platinum(II)]

: 199740-16-4
cis-bis(tert-butylacetylide)bis(diphenyl(tert-butylethynyl)phosphine)platinum

: 199740-23-3
(diphenyl(tert-butylethynyl)phosphine)2Pt(μ-η(1):η(2)-tert-butylacetylide)2Pt(pentafluorophenyl)2

Guidance literature:: In dichloromethane; N2-atmosphere; equimolar amts., stirring for 15 min at room temp.; concn., crystn. on addn. of hexane and standing at -30°C; elem. anal.;
DOI:10.1021/om970663y

Reference yield: 57.0%

: cis-[(pentafluorophenyl)2 (tetrahydrofurane)2 platinum(II)]

: 199740-16-4
cis-bis(tert-butylacetylide)bis(diphenyl(tert-butylethynyl)phosphine)platinum

: 199740-23-3
(diphenyl(tert-butylethynyl)phosphine)2Pt(μ-η(1):η(2)-tert-butylacetylide)2Pt(pentafluorophenyl)2

: 199740-31-3
Pt(μ-κ(P):η(2)-diphenyl(tert-butylethynyl)phosphine)2(μ-η(1):η(2)-tert-butylacetylide)2(Pt(pentafluorophenyl)2)2

Guidance literature:: In dichloromethane; N2-atmosphere; 2 equivs. of Pt(C6F5)2(THF)2, standing for 3 h; evapn., addn. of hexane; elem. anal.;
DOI:10.1021/om970663y