bis(pentafluorophenyl)borinic acid quinolyl ester

Base Information

• Chemical Name: bis(pentafluorophenyl)borinic acid quinolyl ester
• CAS No.: 937030-63-2
• Molecular Formula: C₂₁H₆BF₁₀NO
• Molecular Weight: 489.08
• Mol file: 937030-63-2.mol

Synonyms:bis(pentafluorophenyl)borinic acid quinolyl ester

Chemical Property of bis(pentafluorophenyl)borinic acid quinolyl ester

Chemical Property:

Purity/Quality:

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Technology Process of bis(pentafluorophenyl)borinic acid quinolyl ester

There total 4 articles about bis(pentafluorophenyl)borinic acid quinolyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

8-quinolinol (148-24-3,24804-14-6) + bis(pentafluorophenyl)boron chloride (2720-03-8) → bis(pentafluorophenyl)borinic acid quinolyl ester (937030-63-2)

Guidance literature:

In dichloromethane; byproducts: HCl; (N2); dissolving mixt. of boron compd. and quinoline deriv. in CH2Cl2, stirring at room temp. for 2 h; evapn., elem. anal.;

DOI:10.1039/b700317j

Reference yield: 66.0%

8-quinolinol (148-24-3,24804-14-6) + bromopentafluorobenzene (344-04-7) + diethyl pentafluorophenylboronate → bis(pentafluorophenyl)borinic acid quinolyl ester (937030-63-2)

Guidance literature:

bromopentafluorobenzene; With n-butyllithium; In diethyl ether; at -78 ℃; for 0.5h; Inert atmosphere;

diethyl pentafluorophenylboronate; In diethyl ether; at -78 ℃; for 0.5h; Inert atmosphere;

8-quinolinol; Further stages;

DOI:10.1039/c9dt01332f

Reference yield:

quinolinium tris(pentafluorophenyl)borate (937030-62-1) → bis(pentafluorophenyl)borinic acid quinolyl ester (937030-63-2)

Guidance literature:

In benzene; byproducts: C6F5H; (inert conditions); refluxing boron compd. in benzene;

DOI:10.1039/b700317j

upstream raw materials:

quinolinium tris(pentafluorophenyl)borate

8-quinolinol

bis(pentafluorophenyl)boron chloride

tris(pentafluorophenyl)borate