[Pd(Cl)(κ2N,C-(2,6-dimethylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))]2

Base Information

• Chemical Name: [Pd(Cl)(κ2N,C-(2,6-dimethylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))]2
• CAS No.: 849023-64-9
• Molecular Formula: C₃₆H₄₀Cl₂N₂Pd₂
• Molecular Weight: 784.473
• Mol file: 849023-64-9.mol

Synonyms:[Pd(Cl)(κ2N,C-(2,6-dimethylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))]2

Chemical Property of [Pd(Cl)(κ2N,C-(2,6-dimethylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))]2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of [Pd(Cl)(κ2N,C-(2,6-dimethylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))]2

There total 1 articles about [Pd(Cl)(κ2N,C-(2,6-dimethylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

(2,6-dimethylphenyl)(2,4,6-trimethylbenzylidene)amine + palladium dichloride → [Pd(Cl)(κ2N,C-(2,6-dimethylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))]2 (849023-64-9)

Guidance literature:

With Na acetate; In tetrahydrofuran; acetonitrile; (N2); CH3CN was added to PdCl2; mixt. was stirred at room temp. for 2 d;solvent removed (vac.); ligand, Na acetate and THF were added; mixt. wa s stirred at room temp. for 38 h; solvent removed (vac.); CH2Cl2 added; filtered through Celite; filtrate concd.; residue washed (hexane); elem. anal.;

DOI:10.1021/om049125t

Reference yield: 99.0%

[Pd(Cl)(κ2N,C-(2,6-dimethylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))]2 (849023-64-9) + tricyclohexylphosphine (2622-14-2) → [PdCl(κ2N,C-(2,6-dimethylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))(PCy3)] (849023-67-2)

Guidance literature:

In dichloromethane; (N2); phosphine was added to soln. of Pd complex in CH2Cl2; mixt. was stirred at room temp. for 2 h; solvent evapd.; recrystd. (CH2Cl2/ether); elem. anal.;

DOI:10.1021/om049125t

Reference yield: 99.0%

[Pd(Cl)(κ2N,C-(2,6-dimethylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))]2 (849023-64-9) + triphenylphosphine (603-35-0) → [PdCl(κ2N,C-(2,6-dimethylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))(PPh3)] (849023-71-8)

Guidance literature:

In dichloromethane; (N2); phosphine was added to soln. of Pd complex in CH2Cl2; mixt. was stirred at room temp. for 2 h; solvent evapd.; recrystd. (CH2Cl2/ether); elem. anal.;

DOI:10.1021/om049125t

Downstream raw materials:

[PdCl(κ2N,C-(2,6-dimethylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))(PCy3)]

[PdCl(κ2N,C-(2,6-dimethylphenyl)(2,4,6-trimethylbenzylidene)amine(-1H))(PPh3)]

Refernces