C₃₀H₄₆O₃Si₂

Base Information

• Chemical Name: C₃₀H₄₆O₃Si₂
• CAS No.: 1266178-31-7
• Molecular Formula: C₃₀H₄₆O₃Si₂
• Molecular Weight: 510.864
• Mol file: 1266178-31-7.mol

Synonyms:C₃₀H₄₆O₃Si₂

Chemical Property of C₃₀H₄₆O₃Si₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₀H₄₆O₃Si₂

There total 1 articles about C₃₀H₄₆O₃Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

C30H46O3Si2 → C30H46O3Si2 (1266178-31-7)

Guidance literature:

With silver nitrate; calcium carbonate; In water; acetone; for 4h; Inert atmosphere; Darkness;

DOI:10.1002/anie.201005850

Reference yield: 64.0%

C30H46O3Si2 (1266178-31-7) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → C31H47BrO5Si2 (1266178-33-9)

Guidance literature:

With N-Bromosuccinimide; water; at 10 ℃; for 48h; Inert atmosphere; Darkness;

DOI:10.1002/anie.201005850

Reference yield:

C30H46O3Si2 (1266178-31-7) → C64H90BrNO9Si2

Guidance literature:

Multi-step reaction with 14 steps

1.1: N-Bromosuccinimide; water / 48 h / 10 °C / Inert atmosphere; Darkness

2.1: water; sodium hydrogencarbonate / methanol / Inert atmosphere

3.1: 2,6-dimethylpyridine / dichloromethane / 0 - 20 °C / Inert atmosphere

4.1: trichloroacetic acid / tetrahydrofuran; water / Inert atmosphere

5.1: pyridine; Dess-Martin periodane / dichloromethane / 4 h / 0 °C / Inert atmosphere

6.1: tert.-butyl lithium / diethyl ether; pentane / 0.08 h / -78 °C / Inert atmosphere

6.2: 0.42 h / -78 °C / Inert atmosphere

7.1: pyridine; Dess-Martin periodane / dichloromethane / 0 - 20 °C / Inert atmosphere

8.1: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / -70 °C / Inert atmosphere

9.1: lithium hexamethyldisilazane / tetrahydrofuran / -78 °C / Inert atmosphere

9.2: -78 - 20 °C / Inert atmosphere

10.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane; water / 0 - 20 °C / Inert atmosphere

10.2: Inert atmosphere

11.1: 1H-imidazole; iodine; triphenylphosphine / dichloromethane / 2 h / Inert atmosphere

12.1: lithium diethylamide / tetrahydrofuran / 0.58 h / -78 °C / Inert atmosphere

12.2: 2.5 h / -78 °C / Inert atmosphere

13.1: diisobutylaluminium hydride / toluene / 2.5 h / -40 °C / Inert atmosphere

13.2: -40 °C / Inert atmosphere

14.1: dmap; N-ethyl-N,N-diisopropylamine / dichloromethane / 16 h / 0 - 20 °C / Inert atmosphere

With pyridine; 1H-imidazole; 2,6-dimethylpyridine; dmap; sodium tetrahydroborate; N-Bromosuccinimide; cerium(III) chloride heptahydrate; lithium diethylamide; water; iodine; tert.-butyl lithium; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; N-ethyl-N,N-diisopropylamine; triphenylphosphine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lithium hexamethyldisilazane; trichloroacetic acid; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; toluene; pentane; 5.1: Dess-Martin oxidation / 7.1: Dess-Martin oxidation / 8.1: Luche reduction;

DOI:10.1002/anie.201005850