2,6-dimethyl-4-tert-butylbenzenethiol

Base Information

• Chemical Name: 2,6-dimethyl-4-tert-butylbenzenethiol
• CAS No.: 91638-71-0
• Molecular Formula: C₁₂H₁₈S
• Molecular Weight: 194.341
• Mol file: 91638-71-0.mol

Synonyms:2,6-dimethyl-4-tert-butylbenzenethiol

Chemical Property of 2,6-dimethyl-4-tert-butylbenzenethiol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,6-dimethyl-4-tert-butylbenzenethiol

There total 4 articles about 2,6-dimethyl-4-tert-butylbenzenethiol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.7%

4-tert-butyl-2,6-dimethylbenzene-1-sulfonyl chloride (70823-04-0) → 2,6-dimethyl-4-tert-butylbenzenethiol (91638-71-0)

Guidance literature:

With sulfuric acid; zinc; at 80 ℃; for 4h;

DOI:10.1023/A:1011358501723

Reference yield:

2,6-dimethylbenzene-1-thiol (118-72-9) + 2,6-dimethylphenyl 2-methyl-2-propyl sulfide (16463-11-9) → 2,6-dimethyl-4-tert-butylbenzenethiol (91638-71-0)

Guidance literature:

With boron trifluoride;

DOI:10.1021/jo01072a022

Reference yield:

m-xylene (108-38-3,104809-90-7) → 2,6-dimethyl-4-tert-butylbenzenethiol (91638-71-0)

Guidance literature:

Multi-step reaction with 2 steps

1.1: FeCl₃ / -5 - 20 °C

1.2: 25.66 g / HOSO₂Cl / -5 - 15 °C

2.1: 36.7 percent / conc. H₂SO₄; Zn / 4 h / 80 °C

With sulfuric acid; iron(III) chloride; zinc;

DOI:10.1023/A:1011358501723

upstream raw materials:

2,6-dimethylbenzene-1-thiol

2,6-dimethylphenyl 2-methyl-2-propyl sulfide

4-tert-butyl-2,6-dimethylbenzene-1-sulfonyl chloride

m-xylene

Downstream raw materials:

2',4'-Dinitro-2,6-dimethyl-4-tert.-butyl-diphenylsulfid

4-tert-butyl-2,6-dimethylphenyl trifluoromethyl sulfide