4-Acryloyloxybutyl chloroformate

Base Information

• Chemical Name: 4-Acryloyloxybutyl chloroformate
• CAS No.: 185756-32-5
• Molecular Formula: C₈H₁₁ClO₄
• Molecular Weight: 206.626
• European Community (EC) Number: 606-061-5
• DSSTox Substance ID: DTXSID801272490
• Mol file: 185756-32-5.mol

Synonyms:4-acryloyloxybutyl chloroformate;SCHEMBL343823;HSFWJUIIFWCPBM-UHFFFAOYSA-N;DTXSID801272490;185756-32-5;4-[(Chlorocarbonyl)oxy]butyl 2-propenoate

Chemical Property of 4-Acryloyloxybutyl chloroformate

Chemical Property:

• Vapor Pressure: 0.016mmHg at 25°C
• XLogP3: 2.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 8
• Exact Mass: 206.0345865
• Heavy Atom Count: 13
• Complexity: 191

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C=CC(=O)OCCCCOC(=O)Cl

Technology Process of 4-Acryloyloxybutyl chloroformate

There total 2 articles about 4-Acryloyloxybutyl chloroformate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

4-hydroxybutyl acrylate (2478-10-6,29086-87-1) + bis(trichloromethyl) carbonate (32315-10-9) → 4-(chlorocarbonyloxy)butyl prop-2-enoate (185756-32-5)

Guidance literature:

With pyridine; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; In dichloromethane; at -5 - 20 ℃; for 22.5h; Inert atmosphere;

Reference yield:

→ bis(4'-hydroxybenzoyl)isosorbitol + 4-(chlorocarbonyloxy)butyl prop-2-enoate (185756-32-5)

Guidance literature:

Reference yield: 100.0%

4-(chlorocarbonyloxy)butyl prop-2-enoate (185756-32-5) + 4-hydroxy-benzoic acid (99-96-7) → 4-(4-prop-2-enoyloxybutoxycarbonyloxy)benzoic acid (297132-04-8)

Guidance literature:

4-hydroxy-benzoic acid; With sodium hydroxide; In water; N,N-dimethyl-formamide; pH=10;

4-(chlorocarbonyloxy)butyl prop-2-enoate; With sodium hydroxide; In water; N,N-dimethyl-formamide; at 20 ℃; for 22h; pH=10;

upstream raw materials:

4-hydroxybutyl acrylate

bis(trichloromethyl) carbonate

Downstream raw materials:

4-(4-prop-2-enoyloxybutoxycarbonyloxy)benzoic acid