2-nitro-3-(p-tolylsulfonylmethyl)bicyclo<4.4.1>undeca-1,3,5,7,9-pentaene

Base Information

Chemical Name:2-nitro-3-(p-tolylsulfonylmethyl)bicyclo<4.4.1>undeca-1,3,5,7,9-pentaene
CAS No.:118684-46-1
Molecular Formula:C₁₉H₁₇NO₄S
Molecular Weight:355.414
Hs Code.:

Synonyms:2-nitro-3-(p-tolylsulfonylmethyl)bicyclo<4.4.1>undeca-1,3,5,7,9-pentaene

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Chemical Property of 2-nitro-3-(p-tolylsulfonylmethyl)bicyclo<4.4.1>undeca-1,3,5,7,9-pentaene

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Technology Process of 2-nitro-3-(p-tolylsulfonylmethyl)bicyclo<4.4.1>undeca-1,3,5,7,9-pentaene

There total 3 articles about 2-nitro-3-(p-tolylsulfonylmethyl)bicyclo<4.4.1>undeca-1,3,5,7,9-pentaene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 37891-95-5
bromomethyl 4-tolyl sulfone

: 58790-18-4
(+/-)-2-Nitrobicyclo<4.4.1>undeca-1,3,5,7,9-pentaen

: 118684-46-1
2-nitro-3-(p-tolylsulfonylmethyl)bicyclo<4.4.1>undeca-1,3,5,7,9-pentaene

Guidance literature:: With potassium tert-butylate; In N,N-dimethyl-formamide; at -40 - -30 ℃; for 1.5h;
DOI:10.1007/BF00813207

Reference yield: 40.0%

: 7569-26-8
chloromethyl p-tolylsulfone

: 58790-18-4
(+/-)-2-Nitrobicyclo<4.4.1>undeca-1,3,5,7,9-pentaen

: 118684-46-1
2-nitro-3-(p-tolylsulfonylmethyl)bicyclo<4.4.1>undeca-1,3,5,7,9-pentaene

Guidance literature:: With sodium methylate; In 1,2-dimethoxyethane; at 20 ℃; for 3h;

Reference yield:

: 2443-46-1
1,6-methano[10]annulene

: 118684-46-1
2-nitro-3-(p-tolylsulfonylmethyl)bicyclo<4.4.1>undeca-1,3,5,7,9-pentaene

Guidance literature:: Multi-step reaction with 2 steps

1: Cu(NO₃)2*3H₂O / acetic anhydride / 12 h / 0 °C

2: 40 percent / NaOCH₃ / 1,2-dimethoxy-ethane / 3 h / 20 °C

With sodium methylate; copper(II) nitrate; In 1,2-dimethoxyethane; acetic anhydride;