2-hydroxy-2-<<(tert-butyldiphenylsilyl)oxy>methyl>-1-<(tert-butyldiphenylsilyl)oxy>-4-pentene

Base Information

• Chemical Name: 2-hydroxy-2-<<(tert-butyldiphenylsilyl)oxy>methyl>-1-<(tert-butyldiphenylsilyl)oxy>-4-pentene
• CAS No.: 172843-12-8
• Molecular Formula: C₃₈H₄₈O₃Si₂
• Molecular Weight: 608.968

Synonyms:2-hydroxy-2-<<(tert-butyldiphenylsilyl)oxy>methyl>-1-<(tert-butyldiphenylsilyl)oxy>-4-pentene

Chemical Property of 2-hydroxy-2-<<(tert-butyldiphenylsilyl)oxy>methyl>-1-<(tert-butyldiphenylsilyl)oxy>-4-pentene

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Technology Process of 2-hydroxy-2-<<(tert-butyldiphenylsilyl)oxy>methyl>-1-<(tert-butyldiphenylsilyl)oxy>-4-pentene

There total 2 articles about 2-hydroxy-2-<<(tert-butyldiphenylsilyl)oxy>methyl>-1-<(tert-butyldiphenylsilyl)oxy>-4-pentene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

1,3-bis[[tert-butyl(diphenyl)silyl]oxy]propan-2-one (172843-10-6) + allylmagnesium bromide (1730-25-2) → 2-hydroxy-2-<<(tert-butyldiphenylsilyl)oxy>methyl>-1-<(tert-butyldiphenylsilyl)oxy>-4-pentene (172843-12-8)

Guidance literature:

In tetrahydrofuran; at 0 ℃; for 1h;

DOI:10.1021/jm950276v

Reference yield:

tert-butylchlorodiphenylsilane (58479-61-1) → 2-hydroxy-2-<<(tert-butyldiphenylsilyl)oxy>methyl>-1-<(tert-butyldiphenylsilyl)oxy>-4-pentene (172843-12-8)

Guidance literature:

Multi-step reaction with 2 steps

1: 91 percent / (dimethylamino)pyridine / pyridine / 96 h / Ambient temperature

2: 93 percent / tetrahydrofuran / 1 h / 0 °C

With dmap; In tetrahydrofuran; pyridine;

DOI:10.1021/jm950276v

Reference yield:

2-hydroxy-2-<<(tert-butyldiphenylsilyl)oxy>methyl>-1-<(tert-butyldiphenylsilyl)oxy>-4-pentene (172843-12-8) → 5-(tert-Butyl-diphenyl-silanyloxy)-4-(tert-butyl-diphenyl-silanyloxymethyl)-pentane-1,4-diol

Guidance literature:

With dimethylsulfide borane complex; In tetrahydrofuran; for 24h; Ambient temperature;

DOI:10.1021/jm950276v

upstream raw materials:

1,3-bis[[tert-butyl(diphenyl)silyl]oxy]propan-2-one

allylmagnesium bromide

tert-butylchlorodiphenylsilane

Downstream raw materials:

5,5-Bis-(tert-butyl-diphenyl-silanyloxymethyl)-3-tetradec-(E)-ylidene-dihydro-furan-2-one

5,5-Bis-(tert-butyl-diphenyl-silanyloxymethyl)-3-tetradec-(Z)-ylidene-dihydro-furan-2-one

(E)-5-bis<<(tert-butyldiphenylsilyl)oxy>methyl>-3-<(Z)-9-octadecenylidene>tetrahydro-2-furanone

(Z)-5-bis<<(tert-butyldiphenylsilyl)oxy>methyl>-3-<(Z)-9-octadecenylidene>tetrahydro-2-furanone

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