C₃₆H₃₀ClP₆Rh

Base Information

Chemical Name:C₃₆H₃₀ClP₆Rh
CAS No.:34390-31-3
Molecular Formula:C₃₆H₃₀ClP₆Rh
Molecular Weight:786.835
Hs Code.:

C<sub>36</sub>H<sub>30</sub>ClP<sub>6</sub>Rh

Synonyms:C₃₆H₃₀ClP₆Rh

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Chemical Property of C₃₆H₃₀ClP₆Rh

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Technology Process of C₃₆H₃₀ClP₆Rh

There total 1 articles about C₃₆H₃₀ClP₆Rh which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 14694-95-2
Wilkinson's catalyst

: 12185-10-3
phosphorus

: 34390-31-3
C₃₆H₃₀ClP₆Rh

Guidance literature:: In dichloromethane; under N2 or vac., soln. of P4 in CH2Cl2 added dropwise over 15 min to stirred soln. of RhCl(PPh3)3 in CH2Cl2 at -78°C; solid pptd. by dropwise addn. of Et2O to cold soln., washed with ether, dried at 82°C (0.001 mmHg); elem. anal.;
DOI:10.1021/ja00263a010

Reference yield:

: 34390-31-3
C₃₆H₃₀ClP₆Rh

: 15318-33-9,16353-77-8,13938-94-8
trans-carbonyl(chloro)bis(triphenylphosphine)rhodium(I)

Guidance literature:: With CO; In dichloromethane; RhCl(P4)(PPh3)2 suspended in CH2Cl2 at -78°C, CO passed through suspn. for 2 h; ppt. collected by filtration, washed with ether, dried in vac.; elem. anal.;
DOI:10.1021/ja00263a010

Reference yield:

: 34390-31-3
C₃₆H₃₀ClP₆Rh

: {Rh(((C₆H₅)2PCH₂)2)2}⁽¹⁺⁾*Cl^(1-)*0.25CH₂Cl₂={Rh(((C₆H₅)2PCH₂)2)2}Cl*0.25CH₂Cl₂

Guidance literature:: With bis-(diphenylphosphino)-ethane; methylene chloride; In dichloromethane; under N2 or vac., RhCl(P4)(PPh3)2 suspended in CH2Cl2 at -78°C, excess dppe added, stirred for 4 h; solid pptd. by addn. of ether, collected, washed with ether, dried in vac., recrystd. from CH2Cl2/C6H6, dried at 82°C (0.001 mmHg); elem. anal.;
DOI:10.1021/ja00263a010