1,6-anhydro-3-O-benzyl-4-O-<2,6-bis(benzyloxycarbonylamino)-2,3,4,6-tetradeoxy-α-D-erythro-hexapyranosyl>-2-O-(p-methoxybenzyl)-β-D-glucopyranose

Base Information

Chemical Name:1,6-anhydro-3-O-benzyl-4-O-<2,6-bis(benzyloxycarbonylamino)-2,3,4,6-tetradeoxy-α-D-erythro-hexapyranosyl>-2-O-(p-methoxybenzyl)-β-D-glucopyranose
CAS No.:130222-92-3
Molecular Formula:C₄₃H₄₈N₂O₁₁
Molecular Weight:768.861
Hs Code.:

1,6-anhydro-3-O-benzyl-4-O-<2,6-bis(benzyloxycarbonylamino)-2,3,4,6-tetradeoxy-α-D-erythro-hexapyranosyl>-2-O-(p-methoxybenzyl)-β-D-glucopyranose

Synonyms:1,6-anhydro-3-O-benzyl-4-O-<2,6-bis(benzyloxycarbonylamino)-2,3,4,6-tetradeoxy-α-D-erythro-hexapyranosyl>-2-O-(p-methoxybenzyl)-β-D-glucopyranose

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Chemical Property of 1,6-anhydro-3-O-benzyl-4-O-<2,6-bis(benzyloxycarbonylamino)-2,3,4,6-tetradeoxy-α-D-erythro-hexapyranosyl>-2-O-(p-methoxybenzyl)-β-D-glucopyranose

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Technology Process of 1,6-anhydro-3-O-benzyl-4-O-<2,6-bis(benzyloxycarbonylamino)-2,3,4,6-tetradeoxy-α-D-erythro-hexapyranosyl>-2-O-(p-methoxybenzyl)-β-D-glucopyranose

There total 5 articles about 1,6-anhydro-3-O-benzyl-4-O-<2,6-bis(benzyloxycarbonylamino)-2,3,4,6-tetradeoxy-α-D-erythro-hexapyranosyl>-2-O-(p-methoxybenzyl)-β-D-glucopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 130222-91-2
1,6-anhydro-3-O-benzyl-4-O-<2,6-bis(benzyloxycarbonylamino)-2,3,4,6-tetradeoxy-α-D-erythro-hex-3-enopyranosyl>-2-O-(p-methoxybenzyl)-β-D-glucopyranose

: 130222-92-3
1,6-anhydro-3-O-benzyl-4-O-<2,6-bis(benzyloxycarbonylamino)-2,3,4,6-tetradeoxy-α-D-erythro-hexapyranosyl>-2-O-(p-methoxybenzyl)-β-D-glucopyranose

Guidance literature:: With hydrogen; platinum(IV) oxide; In ethyl acetate; for 48h; under 760 Torr; Ambient temperature;
DOI:10.1246/bcsj.63.1546

Reference yield:

: 110424-94-7
1,6-anhydro-3-O-benzyl-4-O-<2,6-diazido-2,6-dideoxy-3,4-O-isopropylidene-α-D-allopyranosyl>-2-O-(p-methoxybenzyl)-β-D-glucopyranose

: 130222-92-3
1,6-anhydro-3-O-benzyl-4-O-<2,6-bis(benzyloxycarbonylamino)-2,3,4,6-tetradeoxy-α-D-erythro-hexapyranosyl>-2-O-(p-methoxybenzyl)-β-D-glucopyranose

Guidance literature:: Multi-step reaction with 6 steps

1: LiAlH₄ / diethyl ether / 4 h / 0 °C

2: pyridine / CH₂Cl₂ / 1 h / 0 °C

3: 84 percent / 80percent aq. HOAc / 4 h / 60 - 65 °C

4: 87 percent / toluene / 3 h / 80 - 90 °C

5: 76 percent / trimethyl phosphite / 48 h / 110 °C

6: 83 percent / H₂ / PtO₂ / ethyl acetate / 48 h / 760 Torr / Ambient temperature

With pyridine; lithium aluminium tetrahydride; hydrogen; acetic acid; phosphorous acid trimethyl ester; platinum(IV) oxide; In diethyl ether; dichloromethane; ethyl acetate; toluene;
DOI:10.1246/bcsj.63.1546

Reference yield:

: 130222-89-8
1,6-anhydro-3-O-benzyl-4-O-<2,6-bis(benzyloxycarbonylamino)-2,6-dideoxy-α-D-allopyranosyl>-2-O-(p-methoxybenzyl)-β-D-glucopyranose

: 130222-92-3
1,6-anhydro-3-O-benzyl-4-O-<2,6-bis(benzyloxycarbonylamino)-2,3,4,6-tetradeoxy-α-D-erythro-hexapyranosyl>-2-O-(p-methoxybenzyl)-β-D-glucopyranose

Guidance literature:: Multi-step reaction with 3 steps

1: 87 percent / toluene / 3 h / 80 - 90 °C

2: 76 percent / trimethyl phosphite / 48 h / 110 °C

3: 83 percent / H₂ / PtO₂ / ethyl acetate / 48 h / 760 Torr / Ambient temperature

With hydrogen; phosphorous acid trimethyl ester; platinum(IV) oxide; In ethyl acetate; toluene;
DOI:10.1246/bcsj.63.1546