trans-5-<2'-<1''-(dimethyl-t-butylsiloxy)prop-2''-enyl>-1'-methylcyclohexyl>-2-methylpent-1-en-3-one

Base Information

Chemical Name:trans-5-<2'-<1''-(dimethyl-t-butylsiloxy)prop-2''-enyl>-1'-methylcyclohexyl>-2-methylpent-1-en-3-one
CAS No.:115842-83-6
Molecular Formula:C₂₂H₄₀O₂Si
Molecular Weight:364.644
Hs Code.:

Synonyms:trans-5-<2'-<1''-(dimethyl-t-butylsiloxy)prop-2''-enyl>-1'-methylcyclohexyl>-2-methylpent-1-en-3-one

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Chemical Property of trans-5-<2'-<1''-(dimethyl-t-butylsiloxy)prop-2''-enyl>-1'-methylcyclohexyl>-2-methylpent-1-en-3-one

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Technology Process of trans-5-<2'-<1''-(dimethyl-t-butylsiloxy)prop-2''-enyl>-1'-methylcyclohexyl>-2-methylpent-1-en-3-one

There total 1 articles about trans-5-<2'-<1''-(dimethyl-t-butylsiloxy)prop-2''-enyl>-1'-methylcyclohexyl>-2-methylpent-1-en-3-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 109263-23-2,115889-37-7
3-{(1R,2S)-2-[1-(tert-Butyl-dimethyl-silanyloxy)-allyl]-1-methyl-cyclohexyl}-propionaldehyde

: 115842-83-6
trans-5-<2'-<1''-(dimethyl-t-butylsiloxy)prop-2''-enyl>-1'-methylcyclohexyl>-2-methylpent-1-en-3-one

Guidance literature:: Multi-step reaction with 2 steps

1: 68 percent / tetrahydrofuran / 0.5 h / Ambient temperature

2: 74 percent / chromium trioxide, pyridine / CH₂Cl₂ / 0.5 h / Ambient temperature

With pyridine; chromium(VI) oxide; In tetrahydrofuran; dichloromethane;

Reference yield: 85.0%

: 35446-87-8
2,2-bis (phenylseleno)propane

: 115842-83-6
trans-5-<2'-<1''-(dimethyl-t-butylsiloxy)prop-2''-enyl>-1'-methylcyclohexyl>-2-methylpent-1-en-3-one

: 115842-84-7
trans-5-<2'-<1''-(dimethyl-t-butylsiloxy)prop-2''-enyl>-1'-methylcyclohexyl>-3-(1'''-methyl-1'''-phenylselenoethyl)-2-methylpent-1-en-3-ol

Guidance literature:: With n-butyllithium; In tetrahydrofuran; -78 deg C, 1 h, room temperature, 1 h;

Reference yield:

: 115842-83-6
trans-5-<2'-<1''-(dimethyl-t-butylsiloxy)prop-2''-enyl>-1'-methylcyclohexyl>-2-methylpent-1-en-3-one

: 115819-61-9
trans-1-<2'-methyl-2'-<4''-methyl-3''-(1'''-methylvinyl)pent-3''-enyl>cyclohexyl>prop-2-en-1-ol

Guidance literature:: Multi-step reaction with 3 steps

1: 85 percent / butyl-lithium / tetrahydrofuran / -78 deg C, 1 h, room temperature, 1 h

2: 54 percent / thionyl chloride, triethylamine / CH₂Cl₂ / 2 h / Ambient temperature

3: 99 percent / 40percent aq. hydrofluoric acid / acetonitrile / 6 h / Ambient temperature

With n-butyllithium; thionyl chloride; hydrogen fluoride; triethylamine; In tetrahydrofuran; dichloromethane; acetonitrile;