5,5'-((pyridine-3,5-dicarbonyl)bis(azanediyl))diisophthalic acid

Base Information

• Chemical Name: 5,5'-((pyridine-3,5-dicarbonyl)bis(azanediyl))diisophthalic acid
• CAS No.: 1402171-58-7
• Molecular Formula: C₂₃H₁₅N₃O₁₀
• Molecular Weight: 493.386
• Mol file: 1402171-58-7.mol

Synonyms:5,5'-((pyridine-3,5-dicarbonyl)bis(azanediyl))diisophthalic acid

Chemical Property of 5,5'-((pyridine-3,5-dicarbonyl)bis(azanediyl))diisophthalic acid

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 5,5'-((pyridine-3,5-dicarbonyl)bis(azanediyl))diisophthalic acid

There total 2 articles about 5,5'-((pyridine-3,5-dicarbonyl)bis(azanediyl))diisophthalic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

pyridine-3,5-dicarbonyl dichloride (15074-61-0) + 5-aminoisophthalic acid (99-31-0) → 5,5'-((pyridine-3,5-dicarbonyl)bis(azanediyl))diisophthalic acid (1402171-58-7)

Guidance literature:

In acetonitrile; at 20 ℃; Reflux;

DOI:10.1039/c2cc34622b

Reference yield:

3,5-Pyridinedicarboxylic acid (499-81-0) → 5,5'-((pyridine-3,5-dicarbonyl)bis(azanediyl))diisophthalic acid (1402171-58-7)

Guidance literature:

Multi-step reaction with 2 steps

1: thionyl chloride / Inert atmosphere; Reflux

2: dmap / N,N-dimethyl acetamide / 49 h / 0 - 20 °C / Inert atmosphere

With dmap; thionyl chloride; In N,N-dimethyl acetamide;

DOI:10.1002/chem.201504907

Reference yield: 50.0%

manganese(II) chloride tetrahydrate + 5,5'-((pyridine-3,5-dicarbonyl)bis(azanediyl))diisophthalic acid (1402171-58-7) + water (7732-18-5) → C23H11N3O10(4-)*2Mn(2+)*3H2O

Guidance literature:

With potassium hydroxide; at 120 ℃; for 72h; Sealed tube; Autoclave; High pressure;

DOI:10.1515/znb-2017-0104

upstream raw materials:

pyridine-3,5-dicarbonyl dichloride

5-aminoisophthalic acid

3,5-Pyridinedicarboxylic acid