(R)-2-benzyloxycarbonylamino-3-[1-(2-trimethylsilanyl-ethanesulfonyl)-1H-indol-5-yl]-propionic acid methyl ester

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Chemical Name:(R)-2-benzyloxycarbonylamino-3-[1-(2-trimethylsilanyl-ethanesulfonyl)-1H-indol-5-yl]-propionic acid methyl ester
CAS No.:1075706-10-3
Molecular Formula:C₂₅H₃₂N₂O₆SSi
Molecular Weight:516.69
Hs Code.:

Synonyms:(R)-2-benzyloxycarbonylamino-3-[1-(2-trimethylsilanyl-ethanesulfonyl)-1H-indol-5-yl]-propionic acid methyl ester

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Chemical Property of (R)-2-benzyloxycarbonylamino-3-[1-(2-trimethylsilanyl-ethanesulfonyl)-1H-indol-5-yl]-propionic acid methyl ester

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Technology Process of (R)-2-benzyloxycarbonylamino-3-[1-(2-trimethylsilanyl-ethanesulfonyl)-1H-indol-5-yl]-propionic acid methyl ester

There total 1 articles about (R)-2-benzyloxycarbonylamino-3-[1-(2-trimethylsilanyl-ethanesulfonyl)-1H-indol-5-yl]-propionic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 635713-78-9
1-(2-trimethylsilanyl-ethanesulfonyl)-1H-indole-5-carbaldehyde

: 100945-15-1,88568-95-0
N-(benzyloxycarbonyl)phosphonoglycine trimethyl ester

: 1075706-10-3
(R)-2-benzyloxycarbonylamino-3-[1-(2-trimethylsilanyl-ethanesulfonyl)-1H-indol-5-yl]-propionic acid methyl ester

Guidance literature:: N-(benzyloxycarbonyl)phosphonoglycine trimethyl ester; With N,N,N',N'-tetramethylguanidine; In tetrahydrofuran; at 20 ℃; for 0.25h;

1-(2-trimethylsilanyl-ethanesulfonyl)-1H-indole-5-carbaldehyde; In tetrahydrofuran; at -78 - 20 ℃; for 5h;

With (-)-1,2-bis-[(2R,5R)-2,5-diethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate; hydrogen; In methanol; dichloromethane; at 20 ℃; for 2h; under 3102.97 Torr; optical yield given as %ee;
DOI:10.1021/jo801577t

Reference yield: 41.0%

: 1075706-10-3
(R)-2-benzyloxycarbonylamino-3-[1-(2-trimethylsilanyl-ethanesulfonyl)-1H-indol-5-yl]-propionic acid methyl ester

: 635712-73-1
2-benzyloxycarbonylamino-3-(2-oxo-2,3-dihydro-1H-indol-5-yl)propionic acid methyl ester

: 2-benzyloxycarbonylamino-3-(2-oxo-2,3-dihydro-1H-indol-5-yl)propionic acid methyl ester

: 1075706-12-5
2-benzyloxycarbonylamino-3-(2,3-dibromo-1H-indol-5-yl)-propionic acid methyl ester

: 1075706-13-6
C₂₀H₁₇Br₃N₂O₄

Guidance literature:: (R)-2-benzyloxycarbonylamino-3-[1-(2-trimethylsilanyl-ethanesulfonyl)-1H-indol-5-yl]-propionic acid methyl ester; With cesium fluoride; In acetonitrile; at 80 ℃; for 3h;

With pyridinium hydrobromide perbromide; In tert-butyl alcohol; at 20 ℃; for 3.5h;

With acetic acid; zinc; at 20 ℃; optical yield given as %ee;
DOI:10.1021/jo801577t