Technology Process of 3-[1-(6H-dibenzo[b,e]oxepin-11-ylidene)-ethyl]-phenylamine
There total 4 articles about 3-[1-(6H-dibenzo[b,e]oxepin-11-ylidene)-ethyl]-phenylamine which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
hydrogen; triethylamine;
platinum on activated charcoal; sulfided;
In
tetrahydrofuran;
for 2h;
under 2585.74 Torr;
DOI:10.1021/ol060289a
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 89 percent / sodium carbonate / Pd(OAc)2 / dioxane; H2O / 12 h / 70 °C
2: 100 percent / triethylamine; hydrogen / platinum on carbon, sulfided / tetrahydrofuran / 2 h / 2585.74 Torr
With
hydrogen; sodium carbonate; triethylamine;
palladium diacetate; platinum on activated charcoal; sulfided;
In
tetrahydrofuran; 1,4-dioxane; water;
1: Suzuki coupling;
DOI:10.1021/ol060289a
- Guidance literature:
-
Multi-step reaction with 4 steps
1: diethylamine / bis(triphenylphosphine)palladium(II) chloride; copper(I) iodide / 12 h / 20 °C
2: 85 percent / triphenylphosphine; diisopropyl azodicarboxylate / tetrahydrofuran / 12 h / 20 °C
3: 89 percent / sodium carbonate / Pd(OAc)2 / dioxane; H2O / 12 h / 70 °C
4: 100 percent / triethylamine; hydrogen / platinum on carbon, sulfided / tetrahydrofuran / 2 h / 2585.74 Torr
With
di-isopropyl azodicarboxylate; hydrogen; sodium carbonate; diethylamine; triethylamine; triphenylphosphine;
palladium diacetate; copper(l) iodide; platinum on activated charcoal; bis(triphenylphosphine)palladium(II)-chloride; sulfided;
In
tetrahydrofuran; 1,4-dioxane; water;
1: Sonogashira coupling / 2: Mitsunobu reaction / 3: Suzuki coupling;
DOI:10.1021/ol060289a
![(Z)-3-[1-(6H-dibenzo[b,e]oxepin-11-ylidene)-ethyl]-nitrobenzene](/Databaselist/images/loading.webp)
