[1-decarbo-1H-3-oxo-3H-1,5,10,15-tetraphenylporhpyrinato]Ni(II)

Base Information

• Chemical Name: [1-decarbo-1H-3-oxo-3H-1,5,10,15-tetraphenylporhpyrinato]Ni(II)
• CAS No.: 221911-03-1
• Molecular Formula: C₄₃H₂₈N₄NiO
• Molecular Weight: 675.412
• Mol file: 221911-03-1.mol

Synonyms:[1-decarbo-1H-3-oxo-3H-1,5,10,15-tetraphenylporhpyrinato]Ni(II)

Chemical Property of [1-decarbo-1H-3-oxo-3H-1,5,10,15-tetraphenylporhpyrinato]Ni(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [1-decarbo-1H-3-oxo-3H-1,5,10,15-tetraphenylporhpyrinato]Ni(II)

There total 3 articles about [1-decarbo-1H-3-oxo-3H-1,5,10,15-tetraphenylporhpyrinato]Ni(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

[1,4-didecarbo-1H,4H-1,5,10,15-tetraphenylporphyrinato]Ni(II) (221911-04-2) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → [1-decarbo-1H-3-oxo-3H-1,5,10,15-tetraphenylporhpyrinato]Ni(II) (221911-03-1)

Guidance literature:

With trichlorophosphate; In chloroform; at 0 ℃; Reflux; Inert atmosphere;

DOI:10.1016/j.tetlet.2010.06.096

Reference yield: 30.0%

[1,4-didecarbo-1H,4H-1,5,10,15-tetraphenylporphyrinato]Ni(II) (221911-04-2) → [1-decarbo-1H-3-oxo-3H-1,5,10,15-tetraphenylporhpyrinato]Ni(II) (221911-03-1) + [formyl-1,5,10,15-tetraphenylchlorophinato]nickel(II) + [2-hydroxy-5,10,15,20-tetraphenylazeteochlorinato]nickel(II)

Guidance literature:

With POCl₃; In N,N-dimethyl-formamide; 0°C, 20 min, warmed to 60°C for 40 min; quenched by aq. NaHCO3; preparative TLC (silica, CH2Cl2:petroleum ether 30-60);

DOI:10.1016/j.ica.2004.09.015

Reference yield: 7.0%

[2,4-diformyl-1,5,10,15-tetraphenylchlorophinato]nickel(II) (221911-02-0) → [1-decarbo-1H-3-oxo-3H-1,5,10,15-tetraphenylporhpyrinato]Ni(II) (221911-03-1) + [1,4-didecarbo-1H,4H-1,5,10,15-tetraphenylporphyrinato]Ni(II) (221911-04-2) + [2-hydroxy-5,10,15,20-tetraphenylazeteochlorinato]nickel(II)

Guidance literature:

With tris(triphenylphosphine)rhodium(l) chloride; In benzonitrile; toluene; for 72h; Reflux;

DOI:10.1016/j.tetlet.2010.06.096

upstream raw materials:

[1,4-didecarbo-1H,4H-1,5,10,15-tetraphenylporphyrinato]Ni(II)

[2,4-diformyl-1,5,10,15-tetraphenylchlorophinato]nickel(II)

N,N-dimethyl-formamide

Downstream raw materials:

[2-methyl-5.10,15,20-tetraphenylazetochlorinato]nickel(II)

C₄₄H₃₂N₄NiO

[meso-tetraphenyl-2-aza-porphyrinato]nickel(II)