N′-(1-(4-(tert-butyl)phenyl)ethylidene)-4-methylbenzenesulfonohydrazide

Base Information

• Chemical Name: N′-(1-(4-(tert-butyl)phenyl)ethylidene)-4-methylbenzenesulfonohydrazide
• CAS No.: 363588-84-5
• Molecular Formula: C₁₉H₂₄N₂O₂S
• Molecular Weight: 344.478
• Mol file: 363588-84-5.mol

Synonyms:N′-(1-(4-(tert-butyl)phenyl)ethylidene)-4-methylbenzenesulfonohydrazide

Chemical Property of N′-(1-(4-(tert-butyl)phenyl)ethylidene)-4-methylbenzenesulfonohydrazide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N′-(1-(4-(tert-butyl)phenyl)ethylidene)-4-methylbenzenesulfonohydrazide

There total 1 articles about N′-(1-(4-(tert-butyl)phenyl)ethylidene)-4-methylbenzenesulfonohydrazide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

4'-t-butylacetophenone (943-27-1) + toluene-4-sulfonic acid hydrazide (1576-35-8) → N′-(1-(4-(tert-butyl)phenyl)ethylidene)-4-methylbenzenesulfonohydrazide (363588-84-5)

Guidance literature:

With hydrogenchloride; In ethanol; water; at 20 ℃; for 3h;

DOI:10.1021/ol300652k

Reference yield: 96.0%

N′-(1-(4-(tert-butyl)phenyl)ethylidene)-4-methylbenzenesulfonohydrazide (363588-84-5) → 1,4-bis(4-tert-butylphenyl)buta-1,3-diyne (183210-84-6)

Guidance literature:

With 1,4-diaza-bicyclo[2.2.2]octane; oxygen; copper(l) chloride; In dimethyl sulfoxide; at 100 ℃; for 12h; under 760.051 Torr; regioselective reaction; Schlenk technique;

DOI:10.1002/anie.201405058

Reference yield: 86.0%

bromostyrene (103-64-0,1340-14-3) + N′-(1-(4-(tert-butyl)phenyl)ethylidene)-4-methylbenzenesulfonohydrazide (363588-84-5) → (E)-1-phenyl-4-(p-tert-butylphenyl)but-1-en-3-yne (1342799-92-1)

Guidance literature:

With 1,4-diaza-bicyclo[2.2.2]octane; oxygen; copper(l) chloride; In dimethyl sulfoxide; at 100 ℃; for 12h; under 760.051 Torr; regioselective reaction; Schlenk technique;

DOI:10.1002/anie.201405058

upstream raw materials:

4'-t-butylacetophenone

toluene-4-sulfonic acid hydrazide

Downstream raw materials:

4-tert-Butylstyrene

α-deuterio-1-ethenyl-4-tert-butylbenzene

2-(4-(tert-butyl)phenyl)-1-phenylprop-2-en-1-one

4-(4-(tert-butyl)phenyl)-1-(p-tolyl)-1H-1,2,3-triazole