sodium 2-cyano-N-(4-methylphenyl)-3-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosylthio)acrylamide-3-thiolate

Base Information

• Chemical Name: sodium 2-cyano-N-(4-methylphenyl)-3-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosylthio)acrylamide-3-thiolate
• CAS No.: 1158961-99-9
• Molecular Formula: C₂₅H₂₇N₂O₁₀S₂*Na
• Molecular Weight: 602.619
• Mol file: 1158961-99-9.mol

Synonyms:sodium 2-cyano-N-(4-methylphenyl)-3-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosylthio)acrylamide-3-thiolate

Chemical Property of sodium 2-cyano-N-(4-methylphenyl)-3-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosylthio)acrylamide-3-thiolate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of sodium 2-cyano-N-(4-methylphenyl)-3-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosylthio)acrylamide-3-thiolate

There total 1 articles about sodium 2-cyano-N-(4-methylphenyl)-3-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosylthio)acrylamide-3-thiolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + 2-cyano-N-(4-methylphenyl)acetamide (6876-54-6) + 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide (572-09-8) → sodium 2-cyano-N-(4-methylphenyl)-3-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosylthio)acrylamide-3-thiolate (1158961-99-9)

Guidance literature:

carbon disulfide; 2-cyano-N-(4-methylphenyl)acetamide; With sodium ethanolate; In ethanol;

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide; In ethanol; acetone; at 20 ℃; for 9h;

DOI:10.1080/07328300902789209

Reference yield: 78.0%

sodium 2-cyano-N-(4-methylphenyl)-3-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosylthio)acrylamide-3-thiolate (1158961-99-9) → 2-cyano-3-mercapto-N-(4-methylphenyl)-3-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosylthio)acrylamide (1158962-08-3)

Guidance literature:

With acetic acid; In ethanol; water; at 0 ℃; pH=7;

DOI:10.1080/07328300902789209

upstream raw materials:

carbon disulfide

2-cyano-N-(4-methylphenyl)acetamide

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

Downstream raw materials:

2-cyano-3-mercapto-N-(4-methylphenyl)-3-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosylthio)acrylamide