SODIUM BENZYLOXIDE

Base Information

• Chemical Name: SODIUM BENZYLOXIDE
• CAS No.: 20194-18-7
• Molecular Formula: C7H8 O . Na
• Molecular Weight: 130.122
• Hs Code.: 29109000
• Mol file: 20194-18-7.mol

Synonyms:Benzenemethanol,sodium salt (9CI); Benzyl alcohol, sodium salt (8CI); Sodium benzyloxide(6CI,7CI); Sodium benzenemethanolate; Sodium benzoxide; Sodium benzylate;Sodium phenylmethoxide

Chemical Property of SODIUM BENZYLOXIDE

Chemical Property:

• Boiling Point: 203-205 °C
• Flash Point: 194 °F
• PSA: 23.06000
• Density: 1.077 g/mL at 25 °C
• LogP: 1.61710

Purity/Quality:

98%,99%, ^*data from raw suppliers

Sodium benzyloxide solution 1.0M in benzyl alcohol ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 20/21/22-34-20/22
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Uses: This is the sodium salt form of Benzenemethanol. Sodium Benzyloxide is used to desulfurize coal.

Technology Process of SODIUM BENZYLOXIDE

There total 2 articles about SODIUM BENZYLOXIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

benzyl alcohol (100-51-6,185532-71-2) → sodium phenyl-methanolate (20194-18-7)

Guidance literature:

With sodium hydride; In hexane; mineral oil; at 20 ℃; Inert atmosphere;

DOI:10.1002/ejic.201900715

Reference yield:

→ sodium phenyl-methanolate (20194-18-7)

Guidance literature:

Reference yield: 98.0%

1α-Acetyl-1β-chlor-2α-(4-methoxy-phenyl)-cyclohexan (54106-41-1) + sodium phenyl-methanolate (20194-18-7) → 1α-Methyl-2α-(4-methoxy-phenyl)-cyclohexan-1β-carbonsaeurebenzylester (93959-06-9) + benzyl alcohol (100-51-6,185532-71-2)

Guidance literature:

In 1,2-dimethoxyethane; for 4h; Ambient temperature;

upstream raw materials:

benzyl alcohol

Downstream raw materials:

2-benzyloxy-6-ethyl-9-oxo-6,9-dihydro-thiazolo[5,4-f]quinoline-8-carboxylic acid

Phosphorsaeure-(3-benzyloxycarbonylamino-propylester)-benzylester-

benzyl N,N-bis(2-chloroethyl)phosphoramidochloridate

4-(benzyloxy)-2-butanone

Refernces

• 1、 Sánchez-Roa, David,Mosquera, Marta E. G.,Cámpora, Juan. "NHC-CDI Betaine Adducts and Their Cationic Derivatives as Catalyst Precursors for Dichloromethane Valorization". . p. 16725 - 16735. Retrieved 2021/11/18.
• 2、 Lash, Timothy D.,Lamm, Teresa R.,Schaber, J. Andy,Chung, Wen-Hsiang,Johnson, Eric K.,Jones, Marjorie A.. "Normal and abnormal heme biosynthesis. Part 7. Synthesis and metabolism of coproporphyrinogen-III analogues with acetate or butyrate side chains on rings C and D. Development of a modified model for the active site of coproporphyrinogen oxidase". experimental part. p. 1492 - 1504. Retrieved 2011/04/12.