(3S,4R,5R)-5-(13-Benzyloxy-10-oxo-tridecyl)-3,4-dihydroxy-1-(4-methoxy-benzyl)-pyrrolidin-2-one

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Chemical Name:(3S,4R,5R)-5-(13-Benzyloxy-10-oxo-tridecyl)-3,4-dihydroxy-1-(4-methoxy-benzyl)-pyrrolidin-2-one
CAS No.:220831-07-2
Molecular Formula:C₃₂H₄₅NO₆
Molecular Weight:539.712
Hs Code.:

Synonyms:(3S,4R,5R)-5-(13-Benzyloxy-10-oxo-tridecyl)-3,4-dihydroxy-1-(4-methoxy-benzyl)-pyrrolidin-2-one

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Chemical Property of (3S,4R,5R)-5-(13-Benzyloxy-10-oxo-tridecyl)-3,4-dihydroxy-1-(4-methoxy-benzyl)-pyrrolidin-2-one

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Technology Process of (3S,4R,5R)-5-(13-Benzyloxy-10-oxo-tridecyl)-3,4-dihydroxy-1-(4-methoxy-benzyl)-pyrrolidin-2-one

There total 6 articles about (3S,4R,5R)-5-(13-Benzyloxy-10-oxo-tridecyl)-3,4-dihydroxy-1-(4-methoxy-benzyl)-pyrrolidin-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 220831-06-1
(3S,4R,5R)-5-(13-Benzyloxy-10-oxo-tridecyl)-1-(4-methoxy-benzyl)-3,4-bis-triisopropylsilanyloxy-pyrrolidin-2-one

: 220831-07-2
(3S,4R,5R)-5-(13-Benzyloxy-10-oxo-tridecyl)-3,4-dihydroxy-1-(4-methoxy-benzyl)-pyrrolidin-2-one

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran;
DOI:10.1016/S0040-4039(98)02605-7

Reference yield:

: 88476-93-1
10-undecen-1-ylmagnesium bromide

: 220831-07-2
(3S,4R,5R)-5-(13-Benzyloxy-10-oxo-tridecyl)-3,4-dihydroxy-1-(4-methoxy-benzyl)-pyrrolidin-2-one

Guidance literature:: Multi-step reaction with 6 steps

1: 2.) Et₃SiH, BF₃*OEt₂ / 1.) THF, r.t.; 2.) CH₂Cl₂, -78 deg C to -50 deg C

2: 99 percent / OsO₄, NMO / acetone; H₂O

3: NaIO₄ / diethyl ether; H₂O

4: tetrahydrofuran / 0 °C

5: 90 percent / PCC, MS 4A / CH₂Cl₂

6: 92 percent / Bu₄NF / tetrahydrofuran

With triethylsilane; sodium periodate; osmium(VIII) oxide; N-methyl-2-indolinone; boron trifluoride diethyl etherate; tetrabutyl ammonium fluoride; pyridinium chlorochromate; In tetrahydrofuran; diethyl ether; dichloromethane; water; acetone;
DOI:10.1016/S0040-4039(98)02605-7

Reference yield:

: (3S,4S)-1-(4-Methoxy-benzyl)-3,4-bis-triisopropylsilanyloxy-pyrrolidine-2,5-dione

: 220831-07-2
(3S,4R,5R)-5-(13-Benzyloxy-10-oxo-tridecyl)-3,4-dihydroxy-1-(4-methoxy-benzyl)-pyrrolidin-2-one

Guidance literature:: Multi-step reaction with 6 steps

1: 2.) Et₃SiH, BF₃*OEt₂ / 1.) THF, r.t.; 2.) CH₂Cl₂, -78 deg C to -50 deg C

2: 99 percent / OsO₄, NMO / acetone; H₂O

3: NaIO₄ / diethyl ether; H₂O

4: tetrahydrofuran / 0 °C

5: 90 percent / PCC, MS 4A / CH₂Cl₂

6: 92 percent / Bu₄NF / tetrahydrofuran

With triethylsilane; sodium periodate; osmium(VIII) oxide; N-methyl-2-indolinone; boron trifluoride diethyl etherate; tetrabutyl ammonium fluoride; pyridinium chlorochromate; In tetrahydrofuran; diethyl ether; dichloromethane; water; acetone;
DOI:10.1016/S0040-4039(98)02605-7