3-azido-2,4-di-O-benzyl-3-deoxy-α-D-glucopyranosyl-(1→1′)-3'-azido-2′,4',6'-tri-O-benzyl-3'-deoxy-β-D-glucopyranoside

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Chemical Name:3-azido-2,4-di-O-benzyl-3-deoxy-α-D-glucopyranosyl-(1→1′)-3'-azido-2′,4',6'-tri-O-benzyl-3'-deoxy-β-D-glucopyranoside
CAS No.:1430117-31-9
Molecular Formula:C₄₇H₅₀N₆O₉
Molecular Weight:842.949
Hs Code.:

Synonyms:3-azido-2,4-di-O-benzyl-3-deoxy-α-D-glucopyranosyl-(1→1′)-3'-azido-2′,4',6'-tri-O-benzyl-3'-deoxy-β-D-glucopyranoside

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Chemical Property of 3-azido-2,4-di-O-benzyl-3-deoxy-α-D-glucopyranosyl-(1→1′)-3'-azido-2′,4',6'-tri-O-benzyl-3'-deoxy-β-D-glucopyranoside

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Technology Process of 3-azido-2,4-di-O-benzyl-3-deoxy-α-D-glucopyranosyl-(1→1′)-3'-azido-2′,4',6'-tri-O-benzyl-3'-deoxy-β-D-glucopyranoside

There total 3 articles about 3-azido-2,4-di-O-benzyl-3-deoxy-α-D-glucopyranosyl-(1→1′)-3'-azido-2′,4',6'-tri-O-benzyl-3'-deoxy-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1430117-29-5
6-O-acetyl-3-azido-2,4-di-O-benzyl-3-deoxy-α-D-glucopyranosyl-(1→1′)-3'-azido-2′,4′,6'-tri-O-benzyl-3'-deoxy-β-D-glucopyranoside

: 1430117-31-9
3-azido-2,4-di-O-benzyl-3-deoxy-α-D-glucopyranosyl-(1→1′)-3'-azido-2′,4',6'-tri-O-benzyl-3'-deoxy-β-D-glucopyranoside

Guidance literature:: 6-O-acetyl-3-azido-2,4-di-O-benzyl-3-deoxy-α-D-glucopyranosyl-(1→1′)-3'-azido-2′,4′,6'-tri-O-benzyl-3'-deoxy-β-D-glucopyranoside; With sodium; In methanol; for 0.0833333h; Reflux; Inert atmosphere;

In methanol; Cooling;
DOI:10.1021/ja4010255

Reference yield:

: 3-azido-2,4,6-tri-O-benzyl-3-deoxy-D-glucopyranose

: 1430117-31-9
3-azido-2,4-di-O-benzyl-3-deoxy-α-D-glucopyranosyl-(1→1′)-3'-azido-2′,4',6'-tri-O-benzyl-3'-deoxy-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1.1: caesium carbonate / dichloromethane / 4 h / 20 °C / Inert atmosphere

2.1: dichloromethane / 0.5 h / 20 °C / Molecular sieve; Inert atmosphere

2.2: 3 h / -80 - -40 °C / Molecular sieve; Inert atmosphere

3.1: sodium / methanol / 0.08 h / Reflux; Inert atmosphere

3.2: DOWEX 50W-X₈ (H⁺ form) / Cooling

With sodium; caesium carbonate; In methanol; dichloromethane;
DOI:10.1021/ja4010255

Reference yield:

: 1430117-27-3
3-azido-2,4,6-tri-O-benzyl-3-deoxy-α-D-glucopyranosyl trichloroacetimidate

: 1430117-31-9
3-azido-2,4-di-O-benzyl-3-deoxy-α-D-glucopyranosyl-(1→1′)-3'-azido-2′,4',6'-tri-O-benzyl-3'-deoxy-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1.1: dichloromethane / 0.5 h / 20 °C / Molecular sieve; Inert atmosphere

1.2: 3 h / -80 - -40 °C / Molecular sieve; Inert atmosphere

2.1: sodium / methanol / 0.08 h / Reflux; Inert atmosphere

2.2: DOWEX 50W-X₈ (H⁺ form) / Cooling

With sodium; In methanol; dichloromethane;
DOI:10.1021/ja4010255