1,3-bis<4-(methyl acrylate)phenoxymethyl>tetramethyl disiloxane

Base Information

• Chemical Name: 1,3-bis<4-(methyl acrylate)phenoxymethyl>tetramethyl disiloxane
• CAS No.: 114480-37-4
• Molecular Formula: C₂₆H₃₄O₇Si₂
• Molecular Weight: 514.723
• Mol file: 114480-37-4.mol

Synonyms:1,3-bis<4-(methyl acrylate)phenoxymethyl>tetramethyl disiloxane

Chemical Property of 1,3-bis<4-(methyl acrylate)phenoxymethyl>tetramethyl disiloxane

Chemical Property:

Purity/Quality:

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Technology Process of 1,3-bis<4-(methyl acrylate)phenoxymethyl>tetramethyl disiloxane

There total 1 articles about 1,3-bis<4-(methyl acrylate)phenoxymethyl>tetramethyl disiloxane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

1,3-bis(bromomethyl)-1,1,3,3-tetramethyldisiloxane (2351-13-5) + methyl 4-hydroxycinnamate (3943-97-3) → 1,3-bis<4-(methyl acrylate)phenoxymethyl>tetramethyl disiloxane (114480-37-4)

Guidance literature:

With sodium carbonate; In N,N-dimethyl-formamide; at 100 ℃; for 8h;

Reference yield:

1,3-bis<4-(methyl acrylate)phenoxymethyl>tetramethyl disiloxane (114480-37-4) → 1,3-bis<4-(acrylic acid)phenoxymethyl>tetramethyl disiloxane (114480-38-5)

Guidance literature:

With hydrogenchloride; potassium hydroxide; Yield given. Multistep reaction; 1.) 4 h., reflux, 2.) 1 h.;

Reference yield:

1,3-bis<4-(methyl acrylate)phenoxymethyl>tetramethyl disiloxane (114480-37-4) → (E)-3-(4-{3-[4-((E)-2-Chlorocarbonyl-vinyl)-phenoxymethyl]-1,1,3,3-tetramethyl-disiloxanylmethoxy}-phenyl)-acryloyl chloride (114374-55-9)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium hydroxide / aq. ethanol / Heating

2: thionyl chloride / 4 h / Heating

With potassium hydroxide; thionyl chloride; In ethanol;

upstream raw materials:

1,3-bis(bromomethyl)-1,1,3,3-tetramethyldisiloxane

methyl 4-hydroxycinnamate

Downstream raw materials:

1,3-bis<4-(acrylic acid)phenoxymethyl>tetramethyl disiloxane

(E)-3-(4-{3-[4-((E)-2-Chlorocarbonyl-vinyl)-phenoxymethyl]-1,1,3,3-tetramethyl-disiloxanylmethoxy}-phenyl)-acryloyl chloride