1-[(4'S,5'S)-5'-n-hexyl-2',2'-dimethyl-[1,3]-dioxolan-4'-yl]-6-benzyloxyhex-1-ene

Base Information

Chemical Name:1-[(4'S,5'S)-5'-n-hexyl-2',2'-dimethyl-[1,3]-dioxolan-4'-yl]-6-benzyloxyhex-1-ene
CAS No.:689296-84-2
Molecular Formula:C₂₄H₃₈O₃
Molecular Weight:374.564
Hs Code.:

Synonyms:1-[(4'S,5'S)-5'-n-hexyl-2',2'-dimethyl-[1,3]-dioxolan-4'-yl]-6-benzyloxyhex-1-ene

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Chemical Property of 1-[(4'S,5'S)-5'-n-hexyl-2',2'-dimethyl-[1,3]-dioxolan-4'-yl]-6-benzyloxyhex-1-ene

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Technology Process of 1-[(4'S,5'S)-5'-n-hexyl-2',2'-dimethyl-[1,3]-dioxolan-4'-yl]-6-benzyloxyhex-1-ene

There total 2 articles about 1-[(4'S,5'S)-5'-n-hexyl-2',2'-dimethyl-[1,3]-dioxolan-4'-yl]-6-benzyloxyhex-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: (5-benzyloxy)-1-(n-pentyl)triphenylphosphonium bromide

: 689296-78-4
[(4R,5S)-5-(n-hexyl)-2,2-dimethyl-[1,3]-dioxolan-4-yl]carbaldehyde

: 689296-84-2
1-[(4'S,5'S)-5'-n-hexyl-2',2'-dimethyl-[1,3]-dioxolan-4'-yl]-6-benzyloxyhex-1-ene

Guidance literature:: (5-benzyloxy)-1-(n-pentyl)triphenylphosphonium bromide; With n-butyllithium; In diethyl ether; hexane; for 0.0833333h;

[(4R,5S)-5-(n-hexyl)-2,2-dimethyl-[1,3]-dioxolan-4-yl]carbaldehyde; In diethyl ether; hexane; at -78 ℃; for 2h; Further stages.;
DOI:10.1039/b311652b

Reference yield:

: 172547-16-9
(4S,5S)-(5-n-hexyl-2,2-dimethyl-[1,3]-dioxolan-4-yl)methanol

: 689296-84-2
1-[(4'S,5'S)-5'-n-hexyl-2',2'-dimethyl-[1,3]-dioxolan-4'-yl]-6-benzyloxyhex-1-ene

Guidance literature:: Multi-step reaction with 2 steps

1.1: 65 percent / oxalyl chloride; dimethyl sulfoxide; triethylamine / CH₂Cl₂ / 1.5 h / -78 °C

2.1: n-butyl lithium / diethyl ether; hexane / 0.08 h

2.2: 80 percent / diethyl ether; hexane / 2 h / -78 °C

With n-butyllithium; oxalyl dichloride; dimethyl sulfoxide; triethylamine; In diethyl ether; hexane; dichloromethane; 1.1: Swern oxidation;
DOI:10.1039/b311652b