5-benzoylhexahydro-1,3-methanocyclopropapentalen-2(1H)-one

Base Information

Chemical Name:5-benzoylhexahydro-1,3-methanocyclopropapentalen-2(1H)-one
CAS No.:118577-33-6
Molecular Formula:C₁₆H₁₄O₂
Molecular Weight:238.286
Hs Code.:

5-benzoylhexahydro-1,3-methanocyclopropa<c,d>pentalen-2(1H)-one

Synonyms:5-benzoylhexahydro-1,3-methanocyclopropapentalen-2(1H)-one

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Chemical Property of 5-benzoylhexahydro-1,3-methanocyclopropapentalen-2(1H)-one

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Technology Process of 5-benzoylhexahydro-1,3-methanocyclopropapentalen-2(1H)-one

There total 4 articles about 5-benzoylhexahydro-1,3-methanocyclopropapentalen-2(1H)-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: endo,endo-3-benzoyl-2-(diazoacetyl)bicyclo<2.2.1>hept-5-ene

: 118577-33-6
5-benzoylhexahydro-1,3-methanocyclopropapentalen-2(1H)-one

Guidance literature:: With dimethyl acetylenedicarboxylate; rhodium(II) acetate; In benzene; at 25 ℃; for 4h;
DOI:10.1021/jo00265a019

Reference yield:

: 92549-26-3,118577-45-0
endo,endo-3-benzoylbicyclo<2.2.1>hept-5-ene-2-carboxylic acid

: 118577-33-6
5-benzoylhexahydro-1,3-methanocyclopropapentalen-2(1H)-one

Guidance literature:: Multi-step reaction with 3 steps

1: triethylamine / diethyl ether

2: 12 h / 0 - 25 °C

3: 74 percent / dimethyl acetylenedicarboxylate / rhodium(II) acetate / benzene / 4 h / 25 °C

With triethylamine; dimethyl acetylenedicarboxylate; rhodium(II) acetate; In diethyl ether; benzene;
DOI:10.1021/jo00265a019

Reference yield:

: C₁₇H₁₆O₅

: 118577-33-6
5-benzoylhexahydro-1,3-methanocyclopropapentalen-2(1H)-one

Guidance literature:: Multi-step reaction with 2 steps

1: 12 h / 0 - 25 °C

2: 74 percent / dimethyl acetylenedicarboxylate / rhodium(II) acetate / benzene / 4 h / 25 °C

With dimethyl acetylenedicarboxylate; rhodium(II) acetate; In benzene;
DOI:10.1021/jo00265a019